Home
Class 12
CHEMISTRY
Following graph represents a pressure (P...

Following graph represents a pressure `(P)` volume `(V)` relationship at a fixed temperature `(T)` for n moles of a real gas. The graph has two regions marked `(I)` and `(II)`. Which of the following options is true.

A

`Z lt 1` in the region (II)

B

`Z = 1` I the region (II)

C

`Z =1` for the curve

D

`Z` approaches 1 as we move from region (II) to region (I)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the pressure-volume relationship of a real gas at a fixed temperature, we will analyze the graph and the behavior of the gas in the marked regions (I and II). ### Step-by-Step Solution: 1. **Understanding the Graph**: - The graph represents the relationship between pressure (P) and volume (V) for a real gas at a constant temperature (T). - The two regions marked (I) and (II) indicate different behaviors of the gas under varying pressure and volume conditions. 2. **Analyzing Region II**: - In Region II, the pressure is relatively high. Under high pressure, the volume of the gas is small, and the intermolecular forces become significant. - Real gases deviate from ideal behavior in this region, often showing a compressibility factor (Z) less than 1, indicating that attractive forces dominate. 3. **Analyzing Region I**: - In Region I, the pressure is lower and the volume is larger. At low pressure and high volume, the gas molecules are far apart, and the effects of intermolecular forces become negligible. - In this region, the real gas behaves more like an ideal gas, and the compressibility factor (Z) approaches 1. 4. **Comparing Regions**: - As the gas transitions from Region II to Region I, the pressure decreases, and the volume increases. - This transition indicates that the gas is behaving more ideally as it moves to a state of lower pressure and higher volume. 5. **Conclusion**: - The correct statements regarding the behavior of the gas in the two regions are: - In Region II, Z < 1 (indicating non-ideal behavior due to high pressure). - In Region I, Z approaches 1 (indicating ideal behavior due to low pressure). - Therefore, the correct options are A (Z < 1 in Region II) and D (Z approaches 1 in Region I). ### Final Answer: The correct options are A and D.
Promotional Banner

Topper's Solved these Questions

  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise Exercise-3|1 Videos
  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise Exercise-2|1 Videos
  • FUNDAMENTAL CONCEPT

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Fundamental Concept )|40 Videos
  • HYDROCARBON

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Hydrocarbon)|50 Videos

Similar Questions

Explore conceptually related problems

Following represents the Maxwell distribution curve for an ideal gas at two temperature T_(1) and T_(2) . Which of the following option(s) is/are true?

Which of the following graph represents the variation of resistivity ( rho ) with temperature (T) for copper?

An ideal gas has pressure P, volume V and temperature T. Select the correct option.

Figure shows graphs of pressure vs density for an ideal gas at two temperature T_(1) and T_(2) . Which of the following is correct?

The adjoining fgure shows graph of pressure and volume of a gas at two temperatures T_(1) and T_(2) Which one the following is correct

A gas enclosed in a vessel has pressure P, volume V and absolute temperature T, write the formula for number of molecule N of the gas.

A graph between vapour pressure and temperature of few liquids is given below . Study the graph and answer the following : Which of the following statements is true ?

For a fixed mass of gas and constant pressure, which of the following graphs is / are correct?

The vander waal's equation for a gas is (p + a/V^(2))(V - b) = nRT where p, V, R, T and n represent the Pressure, Volume, universal gas constant, absolute temperature and number of moles of a gas respectively, where a and b are constants. The ratio b/a will have the following dimensional formula

RESONANCE ENGLISH-GASEOUS STATE-Exercise
  1. Which of the following is correct for critical temperature ?

    Text Solution

    |

  2. The vander waal gas constant ‘a’ is given by :

    Text Solution

    |

  3. Which of the following are correct statements?

    Text Solution

    |

  4. Select the correct statements(s):

    Text Solution

    |

  5. Which is/are correct for real gases?

    Text Solution

    |

  6. Which of the following statements are incorrect?

    Text Solution

    |

  7. One of the important approach to the study of real gases involves the ...

    Text Solution

    |

  8. One of the important approach to the study of real gases involves the ...

    Text Solution

    |

  9. Following graph represents a pressure (P) volume (V) relationship at a...

    Text Solution

    |

  10. A scientist proposed the following equation of state P = (RT)/(V(m)) -...

    Text Solution

    |

  11. If the critical constants for a hypothetical gas are V(c) = 150 cm^(3)...

    Text Solution

    |

  12. When pressure is increases at constant temp volume of gas decreases AB...

    Text Solution

    |

  13. A gas described by van der Waals equation :

    Text Solution

    |

  14. The term that corrects for the attractive forces present in a real gas...

    Text Solution

    |

  15. For one mole of a van der Waals gas when b = 0 and T = 300 K , the PV ...

    Text Solution

    |

  16. One mole of a monoatomic real gas satisfies the equation p(V-b)= RT w...

    Text Solution

    |

  17. In van der waal's equation of state of the gas law, the constant 'b' i...

    Text Solution

    |

  18. a and b are van der Waals' constants for gases. Chlorine is more easil...

    Text Solution

    |

  19. The compressibility factor (Z) for a real gas under high pressure is ...

    Text Solution

    |

  20. If Z is a compressibility factor, van der Waals equation at low pressu...

    Text Solution

    |