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if element ,(25)X+y has spain magnetric...

if element `,_(25)X+y` has spain magnetric moment 1.732 B.M then:

A

number of unpaired electron `=1`

B

number of unparired electron `=2`

C

`Y=4`

D

`Y=6`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the number of unpaired electrons in the element \( _{25}X^y \) given that its spin magnetic moment is 1.732 Bohr magnetons (B.M). ### Step-by-Step Solution: 1. **Understanding the Magnetic Moment Formula**: The spin magnetic moment (\( \mu_s \)) is given by the formula: \[ \mu_s = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. 2. **Setting Up the Equation**: We know that the magnetic moment is 1.732 B.M. Therefore, we can set up the equation: \[ \sqrt{n(n + 2)} = 1.732 \] 3. **Squaring Both Sides**: To eliminate the square root, we square both sides: \[ n(n + 2) = (1.732)^2 \] Calculating \( (1.732)^2 \): \[ (1.732)^2 = 3 \] Hence, we have: \[ n(n + 2) = 3 \] 4. **Rearranging the Equation**: Rearranging gives us a quadratic equation: \[ n^2 + 2n - 3 = 0 \] 5. **Factoring the Quadratic**: We can factor this quadratic equation: \[ (n + 3)(n - 1) = 0 \] This gives us two possible solutions for \( n \): \[ n + 3 = 0 \quad \Rightarrow \quad n = -3 \quad (\text{not valid since } n \text{ cannot be negative}) \] \[ n - 1 = 0 \quad \Rightarrow \quad n = 1 \] 6. **Conclusion on Unpaired Electrons**: Thus, the number of unpaired electrons \( n \) is 1. 7. **Identifying the Element**: The atomic number 25 corresponds to the element Manganese (Mn). The electronic configuration of Mn is: \[ \text{Mn: } 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^5 \] Manganese has 5 unpaired electrons in its ground state. 8. **Determining the Value of \( y \)**: To achieve 1 unpaired electron, Mn must lose 4 electrons. The electrons will be removed from the 3d subshell first due to its higher energy compared to the 4s subshell. Thus, the new configuration after losing 4 electrons will be: \[ 4s^2 3d^1 \] This configuration has 1 unpaired electron. 9. **Final Answer**: Therefore, the value of \( y \) is 4. ### Summary: The number of unpaired electrons is 1, and the value of \( y \) is 4.
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