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The radial distribution function [P(r)] ...

The radial distribution function `[P(r)]` is used to determine the most probble radius, which is used to find the electron in a givenorbital. `(dp(r))/(dr)` for `1s`- orbital of hydrogen like atom having atomic number Z, is `(dp)/(dr)=(4Z^(3))/(a_(o)"^(3))(2r-(2Zr^(2))/(a_(o)))e^(-2zr//a_(o)):`
Then which of the following statements is/are correct ?

A

At the point maximum value of radial distribution function `(dP(r))/(dr)=0`, one antinode is present

B

Most probable radius of `Li^(2+)` is `a_(0)/3` pm

C

Most probable radius of `He^(+)` is `a_(0)/2` pm

D

Most probable radius of hydrogen atom is `a_(0)` pm

Text Solution

Verified by Experts

The correct Answer is:
A, B, C, D

At the point of maximum value of RDF
`(dP)/(dr)=0`
`(2r-(2Zr^(2))/a_(0))=0, r=a_(0)/Z`
where `Z=3` for `Li^(2+)` and `Z=2` for the `He^(+), Z=1` for hydrogen.
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