Home
Class 12
CHEMISTRY
A hydrogen like atom (atomic number z) i...

A hydrogen like atom (atomic number `z`) is in a higher excited state of quantum number `n`. This excited atom can make a transition to the first excited state by successively emitting two photons of energies `10.2 eV` and `17.0 eV` respectively. Alternatively the atom from the same excited state can make a transition to the second excited state by successively emitting 2 photons of energy `4.25 eV` and`5.95 eV` respectively. Determine the value of `(n+z)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to analyze the transitions of the hydrogen-like atom and use the energy level formula for hydrogen-like atoms to find the values of \( n \) and \( z \). ### Step 1: Understand the Energy Transition Formula The energy difference between two states in a hydrogen-like atom is given by the formula: \[ \Delta E = -13.6 \, \text{eV} \cdot z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( z \) is the atomic number, - \( n_1 \) is the principal quantum number of the lower energy state, - \( n_2 \) is the principal quantum number of the higher energy state. ### Step 2: First Transition to the First Excited State The atom transitions from the excited state \( n \) to the first excited state \( n_1 = 2 \) by emitting two photons with energies \( 10.2 \, \text{eV} \) and \( 17.0 \, \text{eV} \). The total energy emitted is: \[ E_1 = 10.2 \, \text{eV} + 17.0 \, \text{eV} = 27.2 \, \text{eV} \] Using the energy transition formula: \[ 27.2 = 13.6 z^2 \left( \frac{1}{2^2} - \frac{1}{n^2} \right) \] This simplifies to: \[ 27.2 = 13.6 z^2 \left( \frac{1}{4} - \frac{1}{n^2} \right) \] Dividing both sides by \( 13.6 \): \[ 2 = z^2 \left( \frac{1}{4} - \frac{1}{n^2} \right) \] Let this be Equation (1). ### Step 3: Second Transition to the Second Excited State The atom also transitions from the excited state \( n \) to the second excited state \( n_1 = 3 \) by emitting two photons with energies \( 4.25 \, \text{eV} \) and \( 5.95 \, \text{eV} \). The total energy emitted is: \[ E_2 = 4.25 \, \text{eV} + 5.95 \, \text{eV} = 10.2 \, \text{eV} \] Using the energy transition formula: \[ 10.2 = 13.6 z^2 \left( \frac{1}{3^2} - \frac{1}{n^2} \right) \] This simplifies to: \[ 10.2 = 13.6 z^2 \left( \frac{1}{9} - \frac{1}{n^2} \right) \] Dividing both sides by \( 13.6 \): \[ 0.75 = z^2 \left( \frac{1}{9} - \frac{1}{n^2} \right) \] Let this be Equation (2). ### Step 4: Solve the System of Equations Now we have two equations: 1. \( 2 = z^2 \left( \frac{1}{4} - \frac{1}{n^2} \right) \) 2. \( 0.75 = z^2 \left( \frac{1}{9} - \frac{1}{n^2} \right) \) From Equation (1): \[ \frac{1}{n^2} = \frac{1}{4} - \frac{2}{z^2} \] From Equation (2): \[ \frac{1}{n^2} = \frac{1}{9} - \frac{0.75}{z^2} \] Setting both expressions for \( \frac{1}{n^2} \) equal to each other: \[ \frac{1}{4} - \frac{2}{z^2} = \frac{1}{9} - \frac{0.75}{z^2} \] ### Step 5: Solve for \( z^2 \) Rearranging gives: \[ \frac{2}{z^2} - \frac{0.75}{z^2} = \frac{1}{4} - \frac{1}{9} \] Combine the left side: \[ \frac{1.25}{z^2} = \frac{9 - 4}{36} = \frac{5}{36} \] Cross-multiplying gives: \[ 1.25 \cdot 36 = 5 z^2 \] \[ 45 = 5 z^2 \implies z^2 = 9 \implies z = 3 \] ### Step 6: Substitute \( z \) Back to Find \( n \) Substituting \( z = 3 \) back into Equation (1): \[ 2 = 9 \left( \frac{1}{4} - \frac{1}{n^2} \right) \] \[ 2 = \frac{9}{4} - \frac{9}{n^2} \] Multiplying through by \( n^2 \): \[ 2n^2 = \frac{9n^2}{4} - 9 \] Rearranging gives: \[ 8n^2 = 9n^2 - 36 \implies n^2 = 36 \implies n = 6 \] ### Final Calculation of \( n + z \) Now we have \( n = 6 \) and \( z = 3 \): \[ n + z = 6 + 3 = 9 \] ### Final Answer The value of \( n + z \) is \( \boxed{9} \).

To solve the problem step by step, we need to analyze the transitions of the hydrogen-like atom and use the energy level formula for hydrogen-like atoms to find the values of \( n \) and \( z \). ### Step 1: Understand the Energy Transition Formula The energy difference between two states in a hydrogen-like atom is given by the formula: \[ \Delta E = -13.6 \, \text{eV} \cdot z^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: ...
Promotional Banner

Topper's Solved these Questions

  • NUCLEAR CHEMISTRY

    RESONANCE ENGLISH|Exercise PART-III|5 Videos
  • NUCLEAR CHEMISTRY

    RESONANCE ENGLISH|Exercise STAGE-II|1 Videos
  • NUCLEAR CHEMISTRY

    RESONANCE ENGLISH|Exercise ADVANCED LEVEL PROBLEMS|30 Videos
  • NITROGEN CONTAINING COMPOUNDS

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Nitrogen containing Compounds)|30 Videos
  • P BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise PART -II|23 Videos

Similar Questions

Explore conceptually related problems

A hydrogen like atom (atomic number Z) is in a higher excited state of quantum number n. The excited atom can make a transition ot the first excited state by successively emitting two photons of energy 10.2 eV and 17.0 eV, respectively. Alternatively, the atom from the same excited state can make a transition to the second excited state by successively emitting two photons of energies 4.25 eV and 5.95 eV, respectivley Determine the values of n and Z. (lonization energy of H-atom = 13.6 eV)

A hydrogen like species (atomic number Z) is present in a higher excited state of quantum number n. This excited atom can make a transitionn to the first excited state by successive emission of two photons of energies 10.20 eV and 17.0 eV respectively. Altetnatively, the atom from the same excited state can make a transition to the second excited state by successive of two photons of energy 4.25 eV and 5.95 eVv respectively. Determine the value of Z.

A hydrogen like atom (atomic number Z) is in a higher excited satte of quantum number n .This excited atom can make a transition to the first excited state by succesively emitting two photon of energies 10.20 eV and 17.00 eV .Alternatively, the atom from the same excited state can make a transition to the second excited state by successively emitting twio photon of energy 4.25 ev and 5.95 eV Determine the followings: The atom during transition from n = 1 to n = 2 emit radiation in the region of

When a hydrogen atom is excited from ground state to first excited state, then

Energy of H-atom in the ground state is -13.6 eV, hence energy in the second excited state is

The energy of an atom or ion in the first excited state is -13.6 eV. It may be

A hydrogen atom ia in excited state of principal quantum number n . It emits a photon of wavelength lambda when it returnesto the ground state. The value of n is

the energy required to excite an electron in hydrogen atom to its first excited state is

The ground state and first excited state energies of hydrogen atom are -13.6 eV and -3.4eV respectively. If potential energy in ground state is taken to be zero. Then:

A hydrogen like atom of atomic number Z is in an excited state of quantum number 2n. It can emit a maximum energy photon of 204 eV. If it makes a transition to quantum state n, a photon of energy 40.8 eV is emitted. Find n, Z and the ground state energy (in eV) of this atom. Also calculate the minimum energy(eV) that can be emitted by this atom during de - excitation. Ground state energy of hydrogen atom is -13.6 eV

RESONANCE ENGLISH-NUCLEAR CHEMISTRY-PART-II SECTION-1
  1. For a 3s-orbital Phi(3s)=(1)/(asqrt(3))((1)/(a(0)))^(3//2)(6-6sigma+...

    Text Solution

    |

  2. A glow-worm of mass 5.0 g emits red light (650 nm) with a power of 0.1...

    Text Solution

    |

  3. Calculated the energy required to excite one litre of hydrogen gas at ...

    Text Solution

    |

  4. O(2) undergoes photochemical dissociation into one normal oxygen a...

    Text Solution

    |

  5. If the subsidiary quantum number of a subenergy level is 4, the maximu...

    Text Solution

    |

  6. 1 mole of He^(+) ions is excited spectreal anqalysis showed the exist...

    Text Solution

    |

  7. Consider the following six electronic configurations (remaining inner ...

    Text Solution

    |

  8. Choose the correct statement (s) :

    Text Solution

    |

  9. The radial distribution function [P(r)] is used to determine the most ...

    Text Solution

    |

  10. For radial probability curves. Which of the following is/are correct ?

    Text Solution

    |

  11. d(xy) orbital has lobes between x- and y- axes. The wave function of t...

    Text Solution

    |

  12. The dissociation energy of H(2) is 430.53kJ//mol.If H(2) is exposed t...

    Text Solution

    |

  13. The IP(1) of H is 13.6 eV it is expoxed to electromagnetic waves of 1...

    Text Solution

    |

  14. A hydrogen like atom (atomic number z) is in a higher excited state of...

    Text Solution

    |

  15. A moving particle is associated with wavelength 5xx10^(-8) m. If its m...

    Text Solution

    |

  16. According to Bohr's theory, the electronic energy of an electron in t...

    Text Solution

    |

  17. .(4)Be^(7) captures a K electron into its nucleus .What is the mass n...

    Text Solution

    |

  18. Werner Heisenberg considered the limits of how precisely we can measur...

    Text Solution

    |

  19. Werner Heisenberg considered the limits of how precisely we can measur...

    Text Solution

    |

  20. Werner Heisenberg considered the limits of how precisely we can measur...

    Text Solution

    |