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2 moles of ideal gas is expanded isother...

`2` moles of ideal gas is expanded isothermally & reversibly from `1` litre to `10` litre. Find the enthalpy changes in `KJ mol^(-1)`.

A

0

B

`11.7`

C

`-11.7`

D

25

Text Solution

AI Generated Solution

The correct Answer is:
To find the enthalpy change (ΔH) for the isothermal expansion of an ideal gas, we can follow these steps: ### Step 1: Understand the relationship between enthalpy (H), internal energy (U), pressure (P), and volume (V). The enthalpy (H) is defined as: \[ H = U + PV \] ### Step 2: Write the expression for the change in enthalpy (ΔH). The change in enthalpy can be expressed as: \[ \Delta H = \Delta U + \Delta (PV) \] ### Step 3: Use the ideal gas law to express PV. For an ideal gas, we know that: \[ PV = nRT \] where: - n = number of moles of gas - R = ideal gas constant - T = temperature in Kelvin ### Step 4: Analyze the isothermal process. In an isothermal process, the temperature (T) remains constant. Therefore, the change in temperature (ΔT) is zero: \[ \Delta T = 0 \] ### Step 5: Determine the change in internal energy (ΔU). For an ideal gas, the change in internal energy (ΔU) is given by: \[ \Delta U = nC_V \Delta T \] Since ΔT = 0, we have: \[ \Delta U = 0 \] ### Step 6: Determine the change in PV (Δ(PV)). Since temperature is constant, the product PV also changes, but we need to evaluate it: \[ \Delta(PV) = nR\Delta T + \Delta(nRT) \] Again, since ΔT = 0, we find that: \[ \Delta(PV) = 0 \] ### Step 7: Substitute the values into the ΔH equation. Now substituting the values we found: \[ \Delta H = \Delta U + \Delta(PV) = 0 + 0 = 0 \] ### Step 8: Conclusion. Thus, the enthalpy change (ΔH) for the isothermal expansion of the gas is: \[ \Delta H = 0 \, \text{KJ mol}^{-1} \] ### Final Answer: The enthalpy change for the process is **0 KJ mol^(-1)**. ---

To find the enthalpy change (ΔH) for the isothermal expansion of an ideal gas, we can follow these steps: ### Step 1: Understand the relationship between enthalpy (H), internal energy (U), pressure (P), and volume (V). The enthalpy (H) is defined as: \[ H = U + PV \] ### Step 2: Write the expression for the change in enthalpy (ΔH). The change in enthalpy can be expressed as: ...
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