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Statement -1: For every chmical reaction...

Statement -1: For every chmical reaction at equilibrium , standard Gidds energy of reaction is zero
Statement-2: At constant temperature and pressure , chemical reactions are spontaneious in the direction of decreasing gibbs energy.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is not a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is false

D

Statement-1 is False, Statement-2 is True

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the statements provided in the question, we will evaluate each statement based on our understanding of Gibbs free energy and its implications for chemical reactions at equilibrium. ### Step-by-Step Solution: 1. **Understanding Gibbs Free Energy**: - Gibbs free energy (G) is a thermodynamic potential that helps predict the direction of chemical reactions. It is defined as: \[ G = H - TS \] where \(H\) is enthalpy, \(T\) is temperature, and \(S\) is entropy. 2. **Standard Gibbs Free Energy**: - The standard Gibbs free energy change (\( \Delta G^\circ \)) for a reaction is the change in Gibbs free energy when reactants are converted to products under standard conditions (1 bar pressure, 1 M concentration, and a specified temperature). - The relationship between Gibbs free energy change and the equilibrium constant (K) is given by: \[ \Delta G = \Delta G^\circ + RT \ln Q \] where \(Q\) is the reaction quotient. 3. **Evaluating Statement 1**: - Statement 1 claims that "For every chemical reaction at equilibrium, the standard Gibbs energy of reaction is zero." - At equilibrium, the Gibbs free energy change (\( \Delta G \)) is zero, but this does not imply that the standard Gibbs free energy change (\( \Delta G^\circ \)) is also zero. - Therefore, Statement 1 is **incorrect**. 4. **Evaluating Statement 2**: - Statement 2 states that "At constant temperature and pressure, chemical reactions are spontaneous in the direction of decreasing Gibbs energy." - This statement is true because a spontaneous reaction occurs when the Gibbs free energy of the system decreases (\( \Delta G < 0 \)). - As the reaction progresses towards equilibrium, the Gibbs free energy decreases, confirming that Statement 2 is **correct**. 5. **Conclusion**: - Based on the evaluations, Statement 1 is incorrect, and Statement 2 is correct. Therefore, the answer is that Statement 2 is true, while Statement 1 is false. ### Final Answer: - **Statement 1**: Incorrect - **Statement 2**: Correct

To analyze the statements provided in the question, we will evaluate each statement based on our understanding of Gibbs free energy and its implications for chemical reactions at equilibrium. ### Step-by-Step Solution: 1. **Understanding Gibbs Free Energy**: - Gibbs free energy (G) is a thermodynamic potential that helps predict the direction of chemical reactions. It is defined as: \[ G = H - TS ...
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Select correct statements: S_(1) : For every chemical reaction at equilibrium , standard gibbs energy of reaction is zero S_(2) : At constant temperature and pressure , chemical reactions are spontaneous in the direction of decreasing gibbs energy. S_(3) : Spontancity is related to change in entropy if universe.

Assertion (A): For every chemical reaction at equilibrium, standard Gibbs enegry of the reaction is zero. Reason (R ) : At constant temperature and pressure chemical reactions are spontaneous in the direction of the decreasing Gibbs energy.

In the following questions , a statement of assertion (A) is followed by a statement of reason (R). Br A : For every chemical reaction at equilibrium, the value of standard Gibbs free energy change is zero. R: At constant temperature and pressure for a reaction that direction is preferred for which Gibbs free energy increases.

Chemical reaction require energy for

Can activation energy for reactions be zero?

The activation energy of a reaction is zero. The rate constant of this reaction

A reaction attains equilibrium, when the free energy change is

Energy required for start of a chemical reaction is

The free energy change for a reversible reaction at equilibrium is

Identify the correct statement for change of Gibbs energy for a system (DeltaG_(system)) at constant temperature and pressure:

RESONANCE ENGLISH-THERMODYNAMICS-exercise-3 Part:(I)
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