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For his 18th birthday in February Peter ...

For his 18th birthday in February Peter plants to turn a hut in the garden of his parents into a swimming pool with an artifical beach. In order to estimate the consts for heating the water and the house , peter obtains the data for the natural gas combustion and its price.
Calculate the energy (in MJ) which is needed to maintain the temperature inside the house at `30.0^(@)C` during the party (12 hours) .
`1.00 m^(3)` of natural gas as delivered by PUC costs 0.40 € and `1.00 k` Wh of electricity costs 0.137 € . The rent for the equipment for gas heating will cost him about 150.00 € while the corresponding electrical heaters will only cost 100.00 €.

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To solve the problem of calculating the energy needed to maintain the temperature inside Peter's house at 30.0°C during his birthday party for 12 hours, we will break it down into two parts: the energy required to heat the water in the swimming pool and the energy required to heat the air in the house. ### Step 1: Calculate the energy required to heat the water 1. **Determine the volume of water**: - Given volume of water = 22.5 m³. 2. **Convert volume to mass**: - Density of water = 1000 kg/m³. - Mass of water (m) = Volume × Density = 22.5 m³ × 1000 kg/m³ = 22,500 kg. 3. **Calculate the energy required to heat the water**: - Specific heat capacity of water (Cₚ) = 4.18 kJ/kg·°C. - Assume the initial temperature of water is 16°C (for example). - Change in temperature (ΔT) = Final temperature - Initial temperature = 30°C - 16°C = 14°C. - Energy required (E_water) = m × Cₚ × ΔT = 22,500 kg × 4.18 kJ/kg·°C × 14°C. - E_water = 22,500 × 4.18 × 14 = 1,323,060 kJ. ### Step 2: Calculate the energy required to heat the air 1. **Determine the volume of the house**: - Assume dimensions of the house are given as 15 m × 8 m × 3 m. - Volume of the house = 15 m × 8 m × 3 m = 360 m³. 2. **Convert volume to mass**: - Density of air ≈ 1.225 kg/m³. - Mass of air (m_air) = Volume × Density = 360 m³ × 1.225 kg/m³ = 441 kg. 3. **Calculate the energy required to heat the air**: - Specific heat capacity of air (Cₚ) = 1.005 kJ/kg·°C. - Change in temperature (ΔT) = 30°C - 16°C = 14°C. - Energy required (E_air) = m_air × Cₚ × ΔT = 441 kg × 1.005 kJ/kg·°C × 14°C. - E_air = 441 × 1.005 × 14 = 6,141.87 kJ. ### Step 3: Total energy required 1. **Total energy (E_total)**: - E_total = E_water + E_air = 1,323,060 kJ + 6,141.87 kJ = 1,329,201.87 kJ. ### Step 4: Convert to MJ 1. **Convert kJ to MJ**: - 1 MJ = 1000 kJ. - E_total in MJ = 1,329,201.87 kJ / 1000 = 1,329.20 MJ. ### Conclusion The total energy needed to maintain the temperature inside the house at 30.0°C during the party for 12 hours is approximately **1,329.20 MJ**. ---
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For his 18th birthday in February Peter plants to turn a hut in the garden of his parents into a swimming pool with an artifical beach. In order to estimate the consts for heating the water and the house , peter obtains the data for the natural gas combustion and its price. What is the total energy (in MJ) needed for Peter's "winter swimming pool" calculated in 1.3 and 1.4? How much natural gas will he need, if the gas heater has an efficiency of 90.0% ? What are the different costs for the use of either natural gas or electricity ? Use the values given by PUC for your calculations and assume 100% efficiency for the electric heater. Table 1: Composition of natural gas {:("Chemical substance","mol fraction x",D_(1)H^(@)(KJ mol^(-1))^(-1),S^(@)(J mol^(-1)K^(-1))^(-1),C_(p)^(@)(J mol^(-1)K^(-1))^(-1)),(CO_(2(g)),0.0024,-393.5,213.6,37.1),(N_(2(g)) ,0.0134,0.0,191.6,29.1),(CH_(2(g)),0.9732,-74.6,186.3,35.7),(C_(2)H_(3 (g)),0.0110,-84.0,229.2,52.2),(H_(2)O_(g),-,-285.8,70.0,75.3),(H_(2)O_(g),-,-241.8,188.8,33.6),(H_(2)O_(g),-,0.0,205.2,29.4):} Equation J=E(A.Deltat)^(-1) =!! lambda "wall" . DeltaT. d^(-1) , where J= energy flow E along a temperature gradient (wall direction Z) par area A and time Deltat , d-wall thickness , lambda wall -heat conductivity , DeltaT - difference in temperature between the inside and the outside of the house.

For his 18th birthday in February Peter plants to turn a hut in the garden of his parents into a swimming pool with an artifical beach. In order to estimate the consts for heating the water and the house , peter obtains the data for the natural gas combustion and its price. Write down the chemical equations for the complete conbustion of the main components of natural gas, methane and ethane , given in table-1. Assume tht nitrogen is inert under the chosen conditions. Calculate the reaction enthalpy , the reaction entropy , and the Gibbs energy under standard conditons (1.013 xx 10^(5) Pa , 25.0^(@)C) for the combustion of methane and ethane according to the equations above assuming that all products are gaseous . The thermodynamic properties and the composition of natural gas can be found in table 1.

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