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The reaction : Zn(s) + 2AgCl(g) righta...

The reaction :
`Zn(s) + 2AgCl(g) rightarrow ZnCl_(2)(aq) + 2Ag(s)`
occurs in the cell `Zn|ZnCl_(2)` (1M solution), AgCl(s) | Ag. The number of Faradays required from the external source for this reaction to occur in the cell is:

A

2

B

3

C

1

D

zero

Text Solution

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The correct Answer is:
To determine the number of Faradays required for the reaction: \[ \text{Zn}(s) + 2\text{AgCl}(s) \rightarrow \text{ZnCl}_2(aq) + 2\text{Ag}(s) \] we need to analyze the oxidation and reduction processes occurring in the cell. ### Step 1: Identify the oxidation and reduction half-reactions 1. **Oxidation half-reaction**: Zinc (Zn) is oxidized to zinc ions (Zn²⁺). \[ \text{Zn}(s) \rightarrow \text{Zn}^{2+}(aq) + 2e^- \] 2. **Reduction half-reaction**: Silver ions (Ag⁺) are reduced to silver metal (Ag). \[ 2\text{Ag}^+(aq) + 2e^- \rightarrow 2\text{Ag}(s) \] ### Step 2: Balance the overall reaction From the half-reactions, we can see that: - 1 mole of Zn releases 2 moles of electrons. - 2 moles of Ag⁺ consume 2 moles of electrons. This means that the electrons lost by zinc are exactly equal to the electrons gained by silver ions. Therefore, the overall reaction is balanced. ### Step 3: Calculate the total number of moles of electrons transferred In this reaction, a total of 2 moles of electrons are transferred (as indicated by the 2e⁻ in the oxidation half-reaction). ### Step 4: Determine the number of Faradays required 1 Faraday (F) is the charge of 1 mole of electrons, which is approximately 96485 coulombs. Since we have 2 moles of electrons transferred, the number of Faradays required is: \[ \text{Number of Faradays} = \text{moles of electrons} = 2 \text{ F} \] ### Final Answer The number of Faradays required from the external source for this reaction to occur in the cell is **2 Faradays**. ---

To determine the number of Faradays required for the reaction: \[ \text{Zn}(s) + 2\text{AgCl}(s) \rightarrow \text{ZnCl}_2(aq) + 2\text{Ag}(s) \] we need to analyze the oxidation and reduction processes occurring in the cell. ### Step 1: Identify the oxidation and reduction half-reactions ...
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