Home
Class 12
CHEMISTRY
In which of the following cell (s):E(cel...

In which of the following cell (s):`E_(cell)=E_(cell)^(@)`?

A

`Cu(s)|Cu^(2+)(0.01M)||Ag^(+)(0.1M)|Ag(s)`

B

`Pt(H_(2))pH=1||Zn^(2+)(0.01M)|Zn(s)`

C

`Pt(H_(2))|pH=1||Zn^(2+)(1M)|Zn(s)`

D

`Pt(H_(2))|H^(+)=0.1M||Zn^(2+)(0.01M)|Zn(s)`

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

(A). `E_(cell)=E_(cell)^(@)-(0.059)/(2)log(([Ag^(+)]^(2))/([Cu^(2+)]))`
(B). `E_(cell)=E_(cell)^(@)-(0.059)/(2)log(([H^(+)]^(2))/([Zn^(2+)]))`
(D). `E_(cell)=E_(cell)^(@)-(0.059)/(2)log(([H^(+)]^(2))/([Zn^(2+)]))`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISRY

    RESONANCE ENGLISH|Exercise CBSE Problems|34 Videos
  • ELECTRO CHEMISTRY

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (ELECTROCHEMISTRY)|53 Videos
  • EQUIVALENT CONCEPT & TITRATIONS

    RESONANCE ENGLISH|Exercise Part -IV|22 Videos

Similar Questions

Explore conceptually related problems

Write expression of E_(cell) in each of the following cell (i) Zn(s)|ZnSO_(4)(C_(1)M)||CuSO_(4)(C_(2)M)|Cu(s),E_(cell) (ii) Pt|H_(2)(P_(1)atm)||HCl(C_(1)M)|AgCI(s)|Ag,E_(cell) (iii) Pt|Fe^(2+)(C_(1)M),Fe^(+3)(C_(2)M)||Ag^(+)(CM)|Ag,E_(cell)

pH of the solution in the anode compartment of the following cell at 25^@C is x when E_("cell")-E_("cell")^(@)=0.0591V . underset("1 atm")(Pt,H_(2)|pH=X|| Ni^(2+)(M)|Ni Find the value of x.

The e.m.f of the following galvanic cells:

In which case (E_("cell")-E_("cell")^(@)) is zero

The cell in which the following reaction occurs : 2Fe_(aq)^(3+) + 2I_(aq)^(-) to 2Fe_(aq)^(2+) + I_(2(s)) "has" E_("cell")^(o) = 0.236 V "at" 298 K The equilibrium constnat of the cell reaction is

Which of the following cells is // are rechargeable or secondary cell (s) ?

Find the E_(cell)^(@) for the following cell reaction Fe^(+2)+Zn rarr Zn^(+2)+Fe Given E_(Zn//Zn^(+2))^(@)=0.76V,E_(Fe//Fe^(+2))^(@)=+0.41 V

If the E_(cell)^(@) for a given reaction has a positive value, then which of the following gives the correct relationship for the values of DeltaG^(@) and K_(eq) :-

The cell in which the following reaction occurs 2Fe^(3+)(aq)+2I^(-)(aq)to2Fe^(2+)(aq)+I_(2)(aq)+I_(2)(s) has E_(cell)^(0)=0.236V at 298 K. Calculate the standard gibbs energy and the equilibrium constant of the cell reaction.

Which of the following cell organelle is not present in plant cells but present in the animal cell?

RESONANCE ENGLISH-ELECTROCHEMISRY-Advanced Level Problems
  1. During the working of a galvanic cell and with the passage of time.

    Text Solution

    |

  2. Standard electrode potential of two half-reactions are given below: ...

    Text Solution

    |

  3. In which of the following cell (s):E(cell)=E(cell)^(@)?

    Text Solution

    |

  4. Which is/are correct among the following ? Given the half cell emf's E...

    Text Solution

    |

  5. When a solution of conductanes 1.342 mho m^(-1) was placed in a conduc...

    Text Solution

    |

  6. The pK(sp) of AgI is 16.07 if the E^(@) value for Ag^(+)//Ag is 0.7991...

    Text Solution

    |

  7. Voltage of the cell Pt, H(2) (1atm)|HOCN(1.3 xx 10^(-3)M)||Ag^(+) (0....

    Text Solution

    |

  8. K(d) for dissociation of [Ag(NH(3))(2)]^(+) into Ag^(+) and NH(3) is 6...

    Text Solution

    |

  9. The resistance of an aqueous solution containing 0.624g of CuSO(4).5H(...

    Text Solution

    |

  10. Calculate the e.m.f. of the cell Pt|H(2)(1.0atm)|CH(3)COOH (0.1M)||N...

    Text Solution

    |

  11. Calculate the equilibrium concentration of all ions in an ideal soluti...

    Text Solution

    |

  12. The expermental setup for a typical Zn-Ni galvanic cell as shown below...

    Text Solution

    |

  13. At 18^(@)C the mobilities of NH(4)^(+) and CIO(4)^(-) ions are 6.6 xx ...

    Text Solution

    |

  14. 10g fairly concentrated solution of CuSO(4) is electrolyzed using 0.01...

    Text Solution

    |

  15. An electric current is passed through electrolytic cells in series one...

    Text Solution

    |

  16. After electrlysis of NaCI solution with inert electrodes for a certain...

    Text Solution

    |

  17. Same quantity of electricity is being used to liberate iodide (at anod...

    Text Solution

    |

  18. The resistance of two electrolytes X and Y ere found to be 45 and 100 ...

    Text Solution

    |

  19. For 0.0128 N solution fo acetic at 25^(@)C equivalent conductance of t...

    Text Solution

    |

  20. Specific conductance of pure water at 25^(@)C is 0.58 xx 10^(-7) mho c...

    Text Solution

    |