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For the reaction PCl(5(g))hArrPCl(3(g))+...

For the reaction `PCl_(5(g))hArrPCl_(3(g))+Cl_(2(g))`, the forward reaction at constant temperature is favoured by

A

introducing chlorine gas at constant volume

B

introducing an inert gas at constant pressure

C

increasing the volume of the container

D

introducing `PCl_(5)` at constant volume

Text Solution

Verified by Experts

The correct Answer is:
A
According to `K_(p)=P_(PCl_(3)(g)xxP_(Cl_(2)(g)))/(P_(PCl_(5)(g)))=((n_(PCl_(3)(g)))_(eq.)xx(n_(Cl_(2)(g)))_(eq.))/(Vxx(n_(PCl_(5)(g)))_(eg.))`
and on adding inert gas at constant pressure effect on equilibrium will be similar to as if volume of container has been increased.
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