Home
Class 11
CHEMISTRY
consider the following gaseous equilibri...

consider the following gaseous equilibrium with equilibrium constant `K_(1)` and `K_(2)` respectively
`SO_(2)(g)+ 1//2O_(2)hArrSO_(3)(g)`
`2SO_(3)(g)hArr2SO_(2)(g)+O_(2)(g)`
The equilibrium constants are related as

A

`K_(2)=(K_(1))^(-1)`

B

`K_(2)=sqrt((1)/(K_(1))`

C

`K_(2)=((1)/(K_(1)))^(2)`

D

`sqrtK_(1)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the two given equilibrium reactions and their respective equilibrium constants \( K_1 \) and \( K_2 \). ### Step-by-Step Solution: 1. **Identify the Reactions and Their Equilibrium Constants:** - The first reaction is: \[ \text{SO}_2(g) + \frac{1}{2} \text{O}_2(g) \rightleftharpoons \text{SO}_3(g) \] The equilibrium constant for this reaction is \( K_1 \). - The second reaction is: \[ 2 \text{SO}_3(g) \rightleftharpoons 2 \text{SO}_2(g) + \text{O}_2(g) \] The equilibrium constant for this reaction is \( K_2 \). 2. **Write the Expression for \( K_1 \):** - For the first reaction, the equilibrium constant \( K_1 \) can be expressed as: \[ K_1 = \frac{[\text{SO}_3]}{[\text{SO}_2][\text{O}_2]^{1/2}} \] 3. **Write the Expression for \( K_2 \):** - For the second reaction, the equilibrium constant \( K_2 \) can be expressed as: \[ K_2 = \frac{[\text{SO}_2]^2[\text{O}_2]}{[\text{SO}_3]^2} \] 4. **Relate \( K_1 \) and \( K_2 \):** - To relate \( K_1 \) and \( K_2 \), we can manipulate the expression for \( K_2 \): - Rearranging \( K_2 \): \[ K_2 = \frac{[\text{SO}_2]^2[\text{O}_2]}{[\text{SO}_3]^2} \] - Now, notice that if we square \( K_1 \), we get: \[ K_1^2 = \left(\frac{[\text{SO}_3]}{[\text{SO}_2][\text{O}_2]^{1/2}}\right)^2 = \frac{[\text{SO}_3]^2}{[\text{SO}_2]^2[\text{O}_2]} \] - Taking the reciprocal of \( K_1^2 \): \[ \frac{1}{K_1^2} = \frac{[\text{SO}_2]^2[\text{O}_2]}{[\text{SO}_3]^2} = K_2 \] 5. **Final Relationship:** - From the above manipulations, we conclude that: \[ K_2 = \frac{1}{K_1^2} \] ### Conclusion: The relationship between the equilibrium constants \( K_1 \) and \( K_2 \) is: \[ K_2 = \frac{1}{K_1^2} \]
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    RESONANCE ENGLISH|Exercise Advanced Level Problems (Part-3)(Stage-2)|3 Videos
  • CHEMICAL EQUILIBRIUM

    RESONANCE ENGLISH|Exercise Advanced Level Problems (Part-3)(Stage-5)|2 Videos
  • CHEMICAL EQUILIBRIUM

    RESONANCE ENGLISH|Exercise Advanced Level Problems (Part-2)(Section-3)|6 Videos
  • CHEMICAL BONDING

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Fundamental Concept )|6 Videos
  • D & F-BLOCK ELEMENTS & THEIR IMPORTANT COMPOUNDS

    RESONANCE ENGLISH|Exercise Match the column|1 Videos

Similar Questions

Explore conceptually related problems

Consider the following gaseous equilibria with equilibrium constants K_(1) and K_(2) respectively. SO_(2)(g)+1/2O_(2)(g) rarr SO_(3)(g), 2SO_(3)(g) rarr 2SO_(2)(g) + O_(2)(g) The equilibrium constants are related as :

Consider the following gaseous equilibria with equilibrium constant K_(1) "and" K_(2) respectively. SO_(2)(g)+1/2O_(2)(g) rarr SO_(3)(g), 2SO_(3)(g) rarr 2SO_(2)(g) + O_(2)(g) The equilibrium constant are related as :

consider the following gaseous equilibrium with equilibrium constant K_(1) and K_(2) respectively SO_(3)(g)hArrSO_(2)(g)+ 1//2O_(2) 2SO_(3)(g)hArr2SO_(2)(g)+O_(2)(g) The equilibrium constants are related as

Consider the following two gaseous equilibria involving SO_2 and the corresponding equilibrium constants at 298 K: SO_2(g) +(1)/(2) O_2(g) hArr SO_3 (g) ,K1 2SO_3 (g) hArr 2SO_2 (g) + O_2(g) ,K_2 The values of equilibrium constants are related by

At a certain temperature , the following reactions have the equilibrium constants as shown below: S(s)+O_(2)(g)hArrSO_(2)(g),K_(c)=5xx10^(52) 2S(s)+3O_(2)(g)hArr2SO_(3)(g),K_(c)=10^(29) what is the equilibrium constant K_(c) for the reaction at tahea same temperature? 2SO_(2)(g)+O_(2)(g)hArr2SO_(3)(g)

Equilibrium constants K_(1) and K_(2) for the following equilibria NO(g) +1//2O_(2)(g) overset(K_(1))(hArr) NO_(2)(g) and 2NO_(2)(g) overset(K_(2))(hArr)2NO(g)+O_(2)(g) are related as

In the two gaseous reactions (i) and (ii) at 250^@C (i) 2NO(g)+(1)/(2)O_2(g)hArrNO_2(g)K_1 (ii) 2NO_2(g) hArr2NO(g)+O_2(g),K_2 the equilibrium constants K_1 and K_2 are releated as

The equilibrium constant K_(p) for the reaction H_(2)(g)+I_(2)(g) hArr 2HI(g) changes if:

At equilibrium degree of dissociation of SO_(3) is 50% for the reaction 2SO_(3)(g)hArr 2SO_(2)(g)+O_(2)(g) . The equilibrium constant for the reaction is

The equilibrium constant of the reaction SO_(2)(g) + 1//2O_(2)(g)hArrSO_(3)(g) is 4xx10^(-3)atm^(-1//2) . The equilibrium constant of the reaction 2SO_(3)(g)hArr2SO_(2)(g) + O_(2)(g) would be:

RESONANCE ENGLISH-CHEMICAL EQUILIBRIUM-Advanced Level Problems (Part-3)(Stage-1)
  1. For the reaction: 4NH(3)(g)+7O(2(g))hArr4NO(2(g))+6H(2)O(g).K(p) is ...

    Text Solution

    |

  2. When K(c)gt1 for a chemical reaction,

    Text Solution

    |

  3. What will be the effect to increased pressure in the following equilib...

    Text Solution

    |

  4. In which reaction will an increase in the volume of the container favo...

    Text Solution

    |

  5. Which of the following changes the value of the equilibrium constant ?

    Text Solution

    |

  6. Consider the equilibrium reaction: 4NH(3((g)))+3O(2((g)))hArr2N(2((g...

    Text Solution

    |

  7. Equilibrium constants K(1) and K(2) for the following equilibria NO(...

    Text Solution

    |

  8. A catalyst speeds up a chemical reraction by

    Text Solution

    |

  9. For the reaction 2HIhArrH(2)(g)+I(2)(g)

    Text Solution

    |

  10. consider the following gaseous equilibrium with equilibrium constant K...

    Text Solution

    |

  11. The equilibrium constant K(c) for the reaction, 2NaHCO(3)(s)hArrNa(2...

    Text Solution

    |

  12. For the following reaction, the value of K change with N(2)(g)+O(2)(...

    Text Solution

    |

  13. For the reaction PCl(3)(g)+Cl(2)(g)rarrPCl(5)(g),K(c) is 26 at 250^(@)...

    Text Solution

    |

  14. At 445^(@)C,K(c) for the following reaction is 0.020. 2HI(g)rarrH(2)...

    Text Solution

    |

  15. A catalyst accelerates a reaction primarily by stablizing the

    Text Solution

    |

  16. The oxidation of SO(2) to SO(3) is an exothermic reaction. The yield o...

    Text Solution

    |

  17. In which of the following reaction K(p) gt K(c) ?

    Text Solution

    |

  18. The K(p)//K(c) ratio for the reaction: 4NH(3)(g)+7O(2)(g)hArr4NO(g)+...

    Text Solution

    |

  19. K(p) for the reaction given below is 1.36 "at" 499K. Which of the fo...

    Text Solution

    |

  20. At 700K, for the reaction 2SO(2)(g)+O(2)(g)hArr2SO(3)(g) the K(p) "is"...

    Text Solution

    |