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Which of the following statement is corr...

Which of the following statement is correct ?

A

In the dianion , all the `C-C` bonds are of same length but `C-O` bonds are of different length

B

In the dianion, all `C-C` bonds are of same length and also all `C-O` bonds are of same lengths

C

In the dianion, all `C-C` bond lengths are not of same length

D

None of the above

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The correct Answer is:
To determine which statement about the diene anion is correct, we need to analyze the structure and properties of the diene anion. ### Step-by-Step Solution: 1. **Understanding the Diene Anion Structure**: - A diene anion typically has two double bonds and carries a negative charge. The structure can be represented as follows: \[ \text{O}^- - \text{C} = \text{C} - \text{C} = \text{C} - \text{O}^- \] - Here, the carbon atoms (C) are involved in double bonds, and the oxygen atoms (O) carry negative charges. 2. **Analyzing the Carbon-Carbon (C-C) Bonds**: - In a diene anion, the resonance structures allow for delocalization of electrons. This means that the double bonds can shift, leading to equal bond lengths for the C-C bonds. - Therefore, all C-C bonds in the diene anion are of the same length due to resonance. 3. **Analyzing the Carbon-Oxygen (C-O) Bonds**: - The C-O bonds in the diene anion can also be affected by resonance. However, the presence of different types of bonds (single vs. double) can lead to variations in bond lengths. - In this case, the C-O bonds are not necessarily of the same length as the C-C bonds. 4. **Evaluating the Statements**: - **Statement 1**: "In the diene anion, all the C-C bonds are the same length, but the C-O bonds are of different lengths." - This statement is correct. - **Statement 2**: "In the diene anion, all the C-C bonds are the same length, and also all the C-O bonds are the same length." - This statement is incorrect. - **Statement 3**: "In the diene anion, all C-C bond lengths are not the same." - This statement is incorrect. - **Statement 4**: "None of the above." - This statement is incorrect since Statement 1 is correct. 5. **Conclusion**: - The correct statement is **Statement 1**: "In the diene anion, all the C-C bonds are the same length, but the C-O bonds are of different lengths." ### Final Answer: The correct statement is: **In the diene anion, all the C-C bonds are the same length, but the C-O bonds are of different lengths.**
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RESONANCE ENGLISH-GENERAL ORGANIC CHEMISTRY-I-EXERCISE-2 PART-I
  1. The most unlikely representation of resonance structures of p-nitrophe...

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  2. In which of the following carbocations, delocalisation of positive cha...

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  3. Decreasing order of potential energy of the following cations is :

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  4. Stability order of the following species ?

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  5. In which of the following element +1 oxidation state is more stable :

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  6. Which of the following is correct order of stability:

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  7. Least contributing resonating structure of nitroethene is :

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  8. Which of the following statement is correct ?

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  9. The decreasing order of bond length of C=C bond in the following compo...

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  10. Which of the following is correct about the following compound

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  11. The correct order of +M effect of 'N' containing functional group on b...

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  12. In which case the sigma bond pair and pi bond pair of electrons both a...

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  13. The correct stability order of given resonating structures

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  14. The longest C-N bond length in the given compound is :

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  15. Select the correct order of heat of hydrogenation?

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  16. H(3)C-overset(o+)CH-CH=CH(2) does not involve :

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  17. Stability of pi-bond in following alkenes in the increasing order is :...

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  18. In this molecules, pi-electron density is more on :

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  19. If the given compound is planar. Select the correct statement.

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  20. The correct order of electron density in aromatic ring of following co...

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