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Which of the following is the arranged m...

Which of the following is the arranged more stable carbocation of the given species ?
`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-overset(o+)CH-CH_(3)to`

A

`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-underset(o+)CH-CH_(3)`

B

`CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(2)-overset(o+)CH_(2)`

C

`CH_(3)-underset(o+)overset(CH_(3))overset(|)C-overset(CH_(3))overset(|)(CH)-CH_(3)`

D

`CH_(3)-overset(CH_(3))overset(|)C-underset(CH_(3))underset(|)(CH)-overset(o+)CH_(2)`

Text Solution

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The correct Answer is:
To determine the most stable carbocation from the given species, we will analyze the structure and stability of the carbocation. ### Step-by-Step Solution: 1. **Identify the Carbocation**: The given structure is a secondary carbocation (2°) where the positive charge is on a carbon atom that is bonded to two other carbon atoms. 2. **Understanding Carbocation Stability**: Carbocations are classified based on their degree: - Primary (1°) - bonded to one carbon - Secondary (2°) - bonded to two carbons - Tertiary (3°) - bonded to three carbons Tertiary carbocations are the most stable due to hyperconjugation and inductive effects. 3. **Convert to Tertiary Carbocation**: To increase the stability of the carbocation, we can attempt to convert the secondary carbocation into a tertiary carbocation. This can be done by shifting a methyl group from a neighboring carbon to the positively charged carbon. 4. **Methyl Group Shift**: If we shift a methyl group from one of the adjacent carbons to the carbon with the positive charge, we can create a tertiary carbocation. This is done as follows: - Identify a methyl group adjacent to the carbocation and move it to the carbocation center. 5. **Resulting Structure**: After the methyl group shift, the new structure will have the positive charge on a carbon that is now bonded to three other carbon atoms, making it a tertiary carbocation. 6. **Conclusion**: The resulting tertiary carbocation is more stable than the original secondary carbocation due to increased hyperconjugation and inductive stabilization. ### Final Answer: The most stable carbocation among the given species is the tertiary carbocation formed after the methyl group shift. ---
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RESONANCE ENGLISH-GENERAL ORGANIC CHEMISTRY II-Part-II Only One Option Correct Type
  1. The most stable carbocation is:

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  2. Which of the following shows the correct order of decreasing stability...

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  3. Which of the following is the arranged more stable carbocation of the ...

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  4. Most stable rearranged form of given carbocations is:

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  5. Which of the following in the rearranged in the rearranged more stable...

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  6. The correct basic strength order of following anions is:

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  7. Which of the following shows the correct order of decreasing basicity ...

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  8. Find the order of basic strength .(If R=Me) ? (I) R(4)N^(+)OH^(-) " ...

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  9. Which of the following cannot be a base?

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  10. Select the basic strength order of following molecules ?

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  11. Among the following compounds the strongest acid is:

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  12. Which of the following is not correct decreasing k(a) order .

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  13. Which of the following acids has the smallest value of dissociation co...

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  14. Find the strongest acid among the following compounds is:

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  15. Which of the following options shows the correct order of decreasing a...

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  16. Arrange increasing order of acidic strength of following dibasic acids...

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  17. Arrange above phenol in increasing order of pK(a) value:

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  18. Order of K(a) of following acids is:

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  19. Arrange the following compounds in increasing order of their acidic st...

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  20. , The products will be:

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