Home
Class 11
CHEMISTRY
Arrange the following in the order of in...

Arrange the following in the order of increasing stability:
`PhC^(+)H_(2) , Ph_(3)C^(+), Me^(+), Ph_(2)C^(+)H`

A

`Me^(+) lt PhC^(+)He lt Ph_(2)C^(+)H lt Ph_(3)C^(+)`

B

`PhC^(+)H_(2) lt Me^(+) lt Ph_(3)C^(+) lt Ph_(2)C^(+)H`

C

`PhC^(+)H_(2) lt Ph_(3)C^(+) lt Me^(+) lt Ph_(2)C^(+)H`

D

`PhC^(+)H_(2) lt Ph_(2)C^(+)H lt Ph_(3)C^(+) lt Me^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of increasing stability of the given carbocations, we need to analyze each structure based on the number of phenyl (Ph) groups attached and their ability to stabilize the positive charge through resonance. ### Step-by-Step Solution: 1. **Identify the Structures**: - **PhC^(+)H₂**: A phenyl group attached to a carbocation (C^+). - **Ph₃C^(+)**: A carbocation with three phenyl groups attached. - **Me^(+)**: A methyl carbocation (C^+ with three hydrogens). - **Ph₂C^(+)H**: A carbocation with two phenyl groups and one hydrogen. 2. **Assess Stability**: - **Stability of Carbocations**: Carbocations are stabilized by electron-donating groups. The more resonance structures that can be drawn, the more stable the carbocation. - **PhC^(+)H₂**: Has one phenyl group, which can stabilize the positive charge through resonance, but not very effectively. - **Ph₃C^(+)**: Has three phenyl groups, which can delocalize the positive charge very effectively through resonance. This is the most stable carbocation. - **Me^(+)**: A methyl carbocation has no resonance stabilization and is the least stable. - **Ph₂C^(+)H**: Has two phenyl groups, providing some resonance stabilization, but not as much as Ph₃C^(+). 3. **Rank the Stability**: - **Least Stable**: Me^(+) (no resonance stabilization) - **Next**: PhC^(+)H₂ (one phenyl group) - **Next**: Ph₂C^(+)H (two phenyl groups) - **Most Stable**: Ph₃C^(+) (three phenyl groups) ### Final Order of Increasing Stability: 1. Me^(+) < PhC^(+)H₂ < Ph₂C^(+)H < Ph₃C^(+)
Promotional Banner

Topper's Solved these Questions

  • GENERAL ORGANIC CHEMISTRY II

    RESONANCE ENGLISH|Exercise Part-III: Practice Test-2 (IIT-JEE (Advanced Pattern))|16 Videos
  • GENERAL ORGANIC CHEMISTRY II

    RESONANCE ENGLISH|Exercise Part-III: Section-4 : Comprehension Type|3 Videos
  • GENERAL ORGANIC CHEMISTRY II

    RESONANCE ENGLISH|Exercise (APSP) Part-I:Practice Test-1|30 Videos
  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Hydrocarbon)|18 Videos
  • GENERAL ORGANIC CHEMISTRY-I

    RESONANCE ENGLISH|Exercise PART-III : PRACTICE TEST-19|1 Videos

Similar Questions

Explore conceptually related problems

Arrange the following in order of their Increasing basicity: H_(2)O, OH^(-), CH_(3)OH, CH_(3)O^(-)

Arrange the following carbanions in order of their decreasing stability. (I) H_(3)C-C-=C^(-) (II) H-C-=C^(-) (III) H_(3)C-CH_(2)^(-)

Arrange the following in increasing order of reactivity : HCHO, CH_(3)CHO AND C_(6)H_(5)CHO

Arrange the following in increasing order of bond angle PH _(3), SbH_(3), AsH_(3), NH_(3)

Arrange the following in the increasing order of their basic strength : C_(2)H_(5)NH_(2), C_(6)H_(5)NH_(2), (C_(2)H_(5))_(2)NH

Arrange the following in decreasing order of their basic strength : C_(6)H_(5)NH_(2),C_(2)H_(5)NH_(2),(C_(2)H_(5))_(2)NH_(3)

Arrange the following in the order of property indicated for each set : (i) F_(2), Cl_(2) Br_(2),I_(2) - increasing bond dissociation enthalpy. HF,HCl, HBr, HI- increasing acid strength. NH_(3), PH_(3), AsH_(3), SbH_(3), BiH_(3) - increasing base strength.

RESONANCE ENGLISH-GENERAL ORGANIC CHEMISTRY II-Part-II: NSEC (Stage-I)
  1. Which of the following orders is true regarding the acidic nature of p...

    Text Solution

    |

  2. Which of the following order is expected to be correct ?

    Text Solution

    |

  3. Arrange the following in the order of increasing stability: PhC^(+)H...

    Text Solution

    |

  4. Which of the following compounds is the most acidic ?

    Text Solution

    |

  5. The acid having the highest pK(A) value among the following is

    Text Solution

    |

  6. The correct order of acidic character in the above compounds is

    Text Solution

    |

  7. The weakest base among the following is

    Text Solution

    |

  8. The increasing order of basicity for the following intermediates is (f...

    Text Solution

    |

  9. The proper tautomeric structure for 2-aminopyridine (X) is

    Text Solution

    |

  10. The correct order of acidity for the following compounds is

    Text Solution

    |

  11. In which case, the order of acidic strength is not correct?

    Text Solution

    |

  12. The given structures are :

    Text Solution

    |

  13. As the base changes from RNH(2) to R(2)NH(1) to R(3)N the basicity

    Text Solution

    |

  14. Which compound is the most acidic of the following ?

    Text Solution

    |

  15. The order of decreasing stability is :

    Text Solution

    |

  16. The correct order of strengths of the carboxylic acids

    Text Solution

    |

  17. The carbocation (CH(3))(3)C^(+) is stabilized primarily by

    Text Solution

    |

  18. The correct order of acidity for the following compounds is

    Text Solution

    |

  19. Statement I : p -hydroxybenzoic acid has a lower boiling point than o-...

    Text Solution

    |

  20. Which of the following compounds can be hydrolysed?

    Text Solution

    |