Home
Class 11
CHEMISTRY
CH3-undersetunderset(CH3)(|)C=CH2+HBr ov...

`CH_3-undersetunderset(CH_3)(|)C=CH_2+HBr overset(R_2O_2)to` Product is :

A

`CH_3-undersetunderset(CH_3)(|)CH-oversetoverset(Br)(|)CH_2`

B

`CH_3-undersetunderset(CH_3)(|)oversetoverset(Br)(|)C-CH_3`

C

`CH_3-undersetunderset(CH_3)(|)oversetoverset(Br)(|)C-oversetoverset(Br)(|)CH_2`

D

`oversetoverset(Br)(|)CH_2-undersetunderset(CH_3)(|)C=CH_2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product of the reaction between 2-methylpropene (CH₃C(CH₃)=CH₂) and HBr in the presence of R₂O₂, we will follow these steps: ### Step 1: Identify the Reactants We have 2-methylpropene (CH₃C(CH₃)=CH₂) and hydrogen bromide (HBr) as our reactants. The presence of R₂O₂ indicates that we will follow a specific reaction mechanism. **Hint:** Look for the structure of the alkene and the reagent involved. ### Step 2: Understand the Reaction Mechanism The reaction of alkenes with HBr in the presence of peroxides follows the anti-Markovnikov's rule. This means that the bromine (Br) will attach to the carbon with fewer hydrogen atoms, while the hydrogen (H) will attach to the carbon with more hydrogen atoms. **Hint:** Recall the anti-Markovnikov's rule and how it applies to the addition of HBr. ### Step 3: Analyze the Structure of 2-Methylpropene 2-methylpropene has the following structure: - The double bond is between the second and third carbon atoms. - The second carbon (C2) has one hydrogen and one methyl group (C(CH₃)). - The third carbon (C3) has two hydrogens. **Hint:** Identify which carbon has more hydrogens and which has fewer. ### Step 4: Apply Anti-Markovnikov's Rule According to the anti-Markovnikov's rule: - The hydrogen (H) from HBr will attach to the carbon with more hydrogens (C3). - The bromine (Br) will attach to the carbon with fewer hydrogens (C2). **Hint:** Determine which carbon will receive the H and which will receive the Br. ### Step 5: Write the Product Structure After the addition: - The product will have the bromine attached to C2 and the hydrogen attached to C3. - The product structure will be CH₃-CH(CH₃)-CH₂Br. This compound is known as 1-bromo-2-methylpropane. **Hint:** Make sure to visualize the final product structure clearly. ### Final Product The final product of the reaction is **1-bromo-2-methylpropane**. ### Summary of Steps: 1. Identify reactants: 2-methylpropene and HBr. 2. Understand the mechanism: anti-Markovnikov addition due to R₂O₂. 3. Analyze the structure of 2-methylpropene. 4. Apply the rule: H attaches to C3, Br attaches to C2. 5. Write the product: 1-bromo-2-methylpropane.
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISMS - II

    RESONANCE ENGLISH|Exercise Exercise-1 Part-3|2 Videos
  • ORGANIC REACTION MECHANISMS - II

    RESONANCE ENGLISH|Exercise Exercise-2 Part-1|11 Videos
  • ORGANIC REACTION MECHANISMS - II

    RESONANCE ENGLISH|Exercise APSP Part - 3|22 Videos
  • MOLE CONCEPT

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise APSP PART-3|22 Videos

Similar Questions

Explore conceptually related problems

Which of the following statement are correct for give reaction. CH_3-undersetunderset(CH_3)(|)C=CH-CH_3+HBr overset("Peroxide")toCH_3-undersetunderset(CH_3)(|)oversetoverset(Br)(|)C-CH_2-CH_3 " " CH_3-undersetunderset(CH_3)(|)CH-oversetoverset(Br)(|)CH-CH_3

Select the correct statement about the following reaction CH_3-undersetunderset(CH_3)(|)CH-CH_2-CH=CH_2overset(H_2//Ni)to(Y)overset(Cl_2//hv)to Monochloro products

Draw the structure of the major monohalo product in each of the CH_3CH_2 - underset(CH_3)underset(|)C = CH_2 + HBr overset("peroxide")to

CH_3-undersetunderset(O)(||)C-CH_3+PhMgBrtoAoverset(H_3O^+)toBunderset(Delta)overset(H_3PO_4)toC C is :

For the given reaction how many products are optically active (all isomers) : CH_3-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH_2-oversetoverset(CH_3)(|)CH-CH_3overset(Br_2//h upsilon)to

The name of CH_3-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH_2-oversetoverset(CH_3)(|)CH-CH_3 is :

CH_3-oversetoverset(CH_3)(|)C=oversetoverset(CH_3)(|)C-CH_3+HBr toX Product X is :

CH_3-undersetunderset(CH_3)(|)oversetoversetH|C-OH+SOCl_2 to [X] +SO_2+HCl Product [X] is :

What is the major product that will be formed in the following reaction ? CH_3-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH=CH_2+HCl to

RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS - II-Exercise-1 Part-2
  1. Benzene undergoes substituion reaction more easily than addition becau...

    Text Solution

    |

  2. Which one is o, p-directiong group for electrophliic substitution reac...

    Text Solution

    |

  3. In the free-radical chlorination of methane, the chain-intiation step ...

    Text Solution

    |

  4. The maximum ease of abstraction of a hydrogen atom by a chlorine atom ...

    Text Solution

    |

  5. Methane reacts with excess of chlorine is diffused sunlight to give th...

    Text Solution

    |

  6. The above reaction is known as

    Text Solution

    |

  7. In which of the following pairs the bromination of first member is eas...

    Text Solution

    |

  8. Text Solution

    |

  9. CH3-undersetunderset(CH3)(|)C=CH2+HBr overset(R2O2)to Product is :

    Text Solution

    |

  10. One of the following which does not observe the anti-Markovnikoff's ad...

    Text Solution

    |

  11. What are hybridisation states of each carbon atom in the following com...

    Text Solution

    |

  12. Arrange in decreasing order of reactivity with HCl :

    Text Solution

    |

  13. Text Solution

    |

  14. In the given reaction CH(3)-CH=CH-CH(2)-OHoverset(PC C)(to) Product ...

    Text Solution

    |

  15. In which fo the following reaction the product formed by anti markonik...

    Text Solution

    |

  16. Which will form 2,2-Dibromopropane with HBr ?

    Text Solution

    |

  17. Ph-CH(2)-CH=CH(2)overset("dil "H(2)SO(4))rarrA, is

    Text Solution

    |

  18. Text Solution

    |

  19. What is the product when one mole of Pent-1-yne treated with two moles...

    Text Solution

    |

  20. The products obtained via oxymercuration (HgSO(4)+H(2)SO(4)) of 1-buty...

    Text Solution

    |