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The reaction of one equivalent of HBr wi...

The reaction of one equivalent of HBr with
`CH_(2)=CH-C-=CH` gives

A

`CH_2=CH-C-=CBr`

B

`CH_2=CH-undersetunderset(Br)(|)C=CH_2`

C

`CH_3-undersetunderset(Br)(|)CH-C-=CH`

D

`CH_2=CH-CH=CHBr`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of the reaction of one equivalent of HBr with the compound \( CH_2=CH-C \equiv CH \), we will follow these steps: ### Step 1: Identify the Reactant The reactant is an alkyne, specifically 1-butyne, which has the structure \( CH_2=CH-C \equiv CH \). This compound contains both a double bond and a triple bond. ### Step 2: Understand the Reagent The reagent is HBr, which is an unsymmetrical reagent. In HBr, the hydrogen (H) carries a positive charge (H⁺) and bromine (Br) carries a negative charge (Br⁻). ### Step 3: Apply Markovnikov's Rule According to Markovnikov's rule, when an unsymmetrical reagent adds to an unsymmetrical alkene or alkyne, the hydrogen atom (H⁺) will attach to the carbon atom that has the greater number of hydrogen atoms already attached, and the bromine atom (Br⁻) will attach to the carbon atom that has fewer hydrogen atoms. ### Step 4: Analyze the Structure In the compound \( CH_2=CH-C \equiv CH \): - The double bond is between the first and second carbon atoms. - The triple bond is between the second and third carbon atoms. When HBr is added: - The hydrogen (H⁺) will attach to the terminal carbon (the first carbon, \( CH_2 \)), which has more hydrogen atoms. - The bromine (Br⁻) will attach to the second carbon (the one involved in the double bond), which has fewer hydrogen atoms. ### Step 5: Write the Product After the addition of HBr, the product will be: - The double bond between the first and second carbon will become a single bond. - The bromine will be attached to the second carbon. Thus, the product formed will be \( CH_2-CHBr-C \equiv CH \). ### Final Product The final product of the reaction is \( CH_2-CHBr-C \equiv CH \). ### Summary The reaction of one equivalent of HBr with \( CH_2=CH-C \equiv CH \) gives \( CH_2-CHBr-C \equiv CH \). ---
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