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The hydrocarbon that cannot be prepared ...

The hydrocarbon that cannot be prepared effectively by Wurtz reaction is

A

B

C

D

Text Solution

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The correct Answer is:
To determine which hydrocarbon cannot be effectively prepared by the Wurtz reaction, we first need to understand the Wurtz reaction itself and how it operates. ### Step-by-Step Solution: 1. **Understanding the Wurtz Reaction**: - The Wurtz reaction involves the coupling of two alkyl halides (R-X) in the presence of sodium (Na) and dry ether. - The general reaction can be represented as: \[ 2 \, R-X + 2 \, Na \xrightarrow{\text{dry ether}} R-R + 2 \, NaX \] - This reaction typically produces alkanes. 2. **Analyzing the Hydrocarbons**: - We have four hydrocarbons labeled A, B, C, and D. We need to evaluate which of these can be prepared effectively using the Wurtz reaction. - The yield of the desired product is crucial; higher yields are obtained when using similar alkyl halides. 3. **Evaluating Each Option**: - **Option A**: If we take two similar alkyl halides, the yield will be high. - **Option B**: If we use different alkyl halides, we can produce multiple products. For example, if we take two different halides, the reaction can yield several alkenes, leading to a lower yield of the desired product. - **Option C**: Similar to A, if we use two similar alkyl halides, we can achieve a good yield. - **Option D**: If we analyze this option, we find that using two different alkyl halides will also lead to multiple products, thus reducing the yield of the desired hydrocarbon. 4. **Conclusion**: - The hydrocarbon that cannot be prepared effectively by the Wurtz reaction is **Option B** (or D, depending on the specific structures given in the question). The presence of multiple products when different alkyl halides are used leads to a lower yield of the desired hydrocarbon. ### Final Answer: The hydrocarbon that cannot be prepared effectively by the Wurtz reaction is **Option B (or D)**.
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Knowledge Check

  • Which of the following can be prepared by Wurtz reaction?

    A
    `CH_(3)CH_(3)`
    B
    `CH_(3)CH_(2)CH_(2)CH_(3)`
    C
    `H_(3)C-underset(CH_(3))underset(|)CH-CH_(3)`
    D
    `CH_(3)-CH_(2)-underset(CH_(3))underset(|)CH-CH_(3)`
  • is prepared best by the reaction :

    A
    `(CH_(3))_(3)C-Br+(CH_(3))_(3)COKto`
    B
    `(CH_(3))_(3)C-OHunderset(140^(@)C)overset(H_(2)SO_(4))to`
    C
    `(CH_(3))_(3)C-OHunderset(240^(@)C)overset(Al_(2)O_(3))to`
    D
    `(CH_(3))_(2)C=CH_(2)overset("Conc. "H_(2)SO_(4))tooverset((CH_(3))_(3)COH)to`
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