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In which reaction incorrect products hav...

In which reaction incorrect products have been reported.

A

`CH_2=CH-CHO overset(HCl(g)(-10^@C))to undersetunderset(Cl)(|)CH_2-CH_2-CHO`

B

`CH_2=CH-COOH overset(H_2O // H_2SO_4)to undersetunderset(OH)(|)CH_2-CH_2-COOH`

C

`CH_3-oversetoverset(CH_3)(|)C=CH-undersetunderset(O)(||)C-CH_3overset(CH_3OH//H_2SO_4)to CH_3-oversetoverset(CH_3)(|)CH-undersetunderset(OCH_3)(|)CH-undersetunderset(O)(||)C-CH_3`

D

`CH_3-CH=CH-OCH_3overset(CH_3OH//H^+)toCH_3-CH_2-undersetunderset(OCH_3)(|)CH-OCH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine in which reaction incorrect products have been reported, let's analyze each reaction step by step. ### Step 1: Analyze the First Reaction **Reaction:** CH2=CHOH + HCl 1. **Protonation:** The double bond attacks the H+ from HCl, leading to the formation of a carbocation. 2. **Intermediate Formation:** The carbocation is CH2+CH(OH). 3. **Nucleophilic Attack:** Cl- attacks the carbocation, resulting in CH2Cl-CH(OH). 4. **Rearrangement:** The product rearranges to form CH2Cl-CH2-C(=OH) (alcohol). **Conclusion:** The product is correct. ### Step 2: Analyze the Second Reaction **Reaction:** CH2=CHC(=OH) + H2O 1. **Nucleophilic Attack:** Water attacks the double bond, leading to the formation of an alcohol. 2. **Intermediate Formation:** The intermediate is CH2(OH)-CH(OH)-C(=OH). 3. **Rearrangement:** The product rearranges to form CH2(OH)-CH2-C(=OH). **Conclusion:** The product is correct. ### Step 3: Analyze the Third Reaction **Reaction:** CH3-CH=CH-CH(=OH)-CH3 1. **Protonation:** The double bond is protonated, forming a carbocation. 2. **Intermediate Formation:** The carbocation is CH3-CH+-CH(OH)-CH3. 3. **Nucleophilic Attack:** Methanol attacks the carbocation, leading to CH3-CO-CH3-CH(OH). 4. **Rearrangement:** The product rearranges, but here the structure does not lead to a stable product. **Conclusion:** The product is incorrect. ### Step 4: Analyze the Fourth Reaction **Reaction:** CH3-CH2-CH(OH)-CH3 1. **Carbocation Formation:** The hydroxyl group stabilizes the carbocation. 2. **Nucleophilic Attack:** The methanol attacks the carbocation, leading to CH3-CH2-CH(OH)-CH3. 3. **Final Product:** The product formed is stable. **Conclusion:** The product is correct. ### Final Conclusion The incorrect product is from the **third reaction** (option C). ---

To determine in which reaction incorrect products have been reported, let's analyze each reaction step by step. ### Step 1: Analyze the First Reaction **Reaction:** CH2=CHOH + HCl 1. **Protonation:** The double bond attacks the H+ from HCl, leading to the formation of a carbocation. 2. **Intermediate Formation:** The carbocation is CH2+CH(OH). 3. **Nucleophilic Attack:** Cl- attacks the carbocation, resulting in CH2Cl-CH(OH). ...
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RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS - II-APSP Part - 3
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  4. X,Y and Z reaction are :

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  5. The major product of the given reaction is :

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  6. In which reaction incorrect products have been reported.

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  7. In the chlorination of Methane which of the following reaction involve...

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  8. Which of the following reactions are completed through free radical in...

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  9. Which of the following statement are correct for give reaction. CH3-...

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  10. In which of the following reactions and products are correctly matched...

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  11. Which statement is/are correct.

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  12. Which of the following statements is/are incorrect ?

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  13. How many of the following substituents can cause aromatic electrophili...

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  14. How many alkene/s react faster than propane with dil. H(2)SO(4)?

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  15. When addition of Br2 was carried out in presence of aq. NaCl on ethene...

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  16. How many reactions will proceed through free radical addition mechanis...

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  17. In the given reactions M is the number of major products obtained in I...

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