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Bromocyclodecane on heating with ethanol...

Bromocyclodecane on heating with ethanolic KOH, produces two alkenes. Write the two products also mentions the major one.

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To solve the problem of what products are formed when bromocyclodecane is heated with ethanolic KOH, we can follow these steps: ### Step 1: Understand the Reactant Bromocyclodecane is a cyclic alkane with a bromine atom attached. The structure can be represented as follows: ``` Br | C1 - C2 / \ C10 C3 | | C9 C4 | | C8 C5 \ / C7 - C6 ``` ### Step 2: Identify the Reaction Type When bromocyclodecane is treated with ethanolic KOH, an elimination reaction occurs. This is typically an E2 elimination where the bromine atom is removed along with a hydrogen atom from an adjacent carbon. ### Step 3: Determine Possible Elimination Sites In bromocyclodecane, elimination can occur from two different positions: 1. Removing a hydrogen from the carbon adjacent to the carbon with the bromine (C1 or C2). 2. This can lead to the formation of two different alkenes. ### Step 4: Draw the Possible Products 1. **Cis Product**: When elimination occurs between C1 and C2, the product formed is a cis-alkene. 2. **Trans Product**: When elimination occurs between C1 and C2 but from the opposite side, the product formed is a trans-alkene. The structures can be represented as follows: - **Cis Product**: ``` H \ C1 = C2 / \ C10 C3 | | C9 C4 | | C8 C5 \ / C7 - C6 ``` - **Trans Product**: ``` H \ C1 = C2 / \ C10 C3 | | C9 C4 | | C8 C5 \ / C7 - C6 ``` ### Step 5: Identify the Major Product In elimination reactions, the stability of the alkene plays a crucial role in determining the major product. Generally, the more substituted alkene is more stable and thus is favored in elimination reactions. In this case, the **cis product** is more stable due to steric factors and is therefore the major product. The **trans product** is less stable and is the minor product. ### Conclusion The two products formed from the reaction of bromocyclodecane with ethanolic KOH are: 1. **Cis-alkene** (major product) 2. **Trans-alkene** (minor product)
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RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS-IV-APSP PART-3
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