Home
Class 11
CHEMISTRY
CH3-undersetunderset(CH3)(|)CH-underset(...

`CH_3-undersetunderset(CH_3)(|)CH-underset(Cl)underset(|)(CH)-CH_3 overset(EtOH//Delta)to` Major elimination product X.
X is :

A

`CH_3-oversetoverset(CH_3)(|)CH-CH=CH_3`

B

`CH_3-oversetoverset(CH_3)(|)C=CH-CH_3`

C

`CH_3-overset(C_2H_5)overset(|)C=CH_2`

D

`CH_3-oversetoverset(CH_3)(|)C=oversetoverset(CH_3)(|)C-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of determining the major elimination product (X) from the given compound when reacted with ethanol (EtOH) under heat, we will follow these steps: ### Step 1: Identify the Structure of the Starting Compound The starting compound is: \[ CH_3 - C(CH_3)(Cl) - C(CH_3) - CH_3 \] This compound has a chlorine atom (Cl) attached to a carbon that is also bonded to two methyl groups (CH3). ### Step 2: Determine the Type of Reaction Since we are reacting with ethanol (EtOH) in the presence of heat, we expect an elimination reaction to occur. Given that EtOH is a strong base, the reaction will likely follow the E2 mechanism, which is characterized by a concerted elimination of a leaving group (in this case, Cl) and a hydrogen atom from an adjacent carbon. ### Step 3: Identify Possible Elimination Products In an E2 reaction, the elimination will occur between the carbon bearing the chlorine and a hydrogen atom from a neighboring carbon. The possible elimination products can be determined by considering the removal of Cl and a hydrogen atom from adjacent carbons. 1. **Product 1**: If we remove Cl from the carbon attached to Cl and a hydrogen from the adjacent carbon, we can form: \[ CH_3 - C(CH_3) = C(CH_3) - CH_3 \] This results in a double bond between the second and third carbons. 2. **Product 2**: Alternatively, if we remove Cl and a hydrogen from the other adjacent carbon, we can form: \[ CH_3 - C(CH_3) - C(CH_3) = CH_3 \] This results in a double bond between the first and second carbons. ### Step 4: Apply the Zaitsev's Rule According to Zaitsev's rule, the more substituted alkene is generally the major product in elimination reactions. - **Product 1** has a double bond between the second and third carbons and has three substituents on the double bond. - **Product 2** has a double bond between the first and second carbons and has only one substituent on the double bond. ### Step 5: Determine the Major Product Since Product 1 is more substituted (with three alkyl groups attached to the double bond), it will be the more stable and thus the major product formed during the reaction. ### Conclusion The major elimination product X is: \[ CH_3 - C(CH_3) = C(CH_3) - CH_3 \] ### Final Answer X is: **CH3-CH(CH3)=C(CH3)-CH3** ---
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise Exercise-1 Part-3|2 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise Exercise-2 Part-1|11 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise APSP PART-3|22 Videos
  • ORGANIC REACTION MECHANISMS - II

    RESONANCE ENGLISH|Exercise APSP Part - 3|22 Videos
  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos

Similar Questions

Explore conceptually related problems

CH_3-undersetunderset(CH_3)(|)CH-oversetoverset(Cl)(|)CH-CH_3 underset(Delta)overset(t-BuO) to Major Product is :

CH_(3)-underset(Cl)underset(|)(CH)-underset(CH_(3))underset(|)(CH)-CH_(3)+"Alcoholic KOH"overset(Delta)(to) (A) major + B (minor). A and B are:

CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH=CH-CH_(3)overset(H-Cl)(to) ?

CH_(3)-underset(O)underset(||)C-CH=CH-CH_(3)overset(HBr)rarr find the major product

In the given reaction, CH_(3)-underset(CH_3)underset(|)(CH)-overset(O)overset(||)(C )-CH_2-CH_3 overset(CF_3CO_3H)(rarr)(X) as main product, 'X' will be

Consider the following reaction: CH_(3)underset(D)underset(|)CH-underset(CH_(3))underset(|)(CH)CH_(3)+overset(.)BrrarrX+HBr Identify the structure of the major products (X) from among the following :

CH_3-CH_2-undersetunderset(CH_3)(|)oversetoverset(Cl)(|)C-CH_2-CH_3overset(80% EtOH)to What is/are true about above reaction ?

CH_(3)-underset(CH_3)underset(|)overset(CH_3)overset(|)(C )-underset(Br)underset(|)(C )H-CH_(3) underset(Delta)overset("El mechanism")(rarr) (A) Major product (A) is

The products (A) and (B) are respectively. (i) CH_3-underset(Br)underset(|)(CH)-underset(CH_3)underset(|)(CH)-CH_3overset(C_2H_5ONa)to(A) (ii) CH_2=overset(CH_3)overset(|)(C)-CH_2CH_3underset("Peroxide")overset(HBr)to(B)

RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS-IV-Exercise-1 Part-2
  1. Which of the following reaction is an example of elimination reaction ...

    Text Solution

    |

  2. Correct statement for E1 Reaction is :

    Text Solution

    |

  3. Intermediate formed during E2 reaction is -

    Text Solution

    |

  4. CH3-undersetunderset(CH3)(|)CH-underset(Cl)underset(|)(CH)-CH3 overset...

    Text Solution

    |

  5. CH3-undersetunderset(OH)(|)oversetoverset(CH3)(|)C-CH3 undersetDeltaov...

    Text Solution

    |

  6. In the given reaction : overset(Conc. H2SO4)to [X] as major produ...

    Text Solution

    |

  7. Identify the major formed in the following reaction

    Text Solution

    |

  8. Which of the following does not represent the correct product?

    Text Solution

    |

  9. Correct statement for E1 Reaction is :

    Text Solution

    |

  10. Intermediate formed during E2 reaction is -

    Text Solution

    |

  11. CH3-undersetunderset(H)(|)oversetoverset(CH3)(|)C-CH2Br underset(Delta...

    Text Solution

    |

  12. Which of the following compounds undergo E2 reaction with maximum rate...

    Text Solution

    |

  13. 2-Chlorobutane on treatment with alcoholic KOH/Delta gives major produ...

    Text Solution

    |

  14. CH3-undersetunderset(CH3)(|)CH-oversetoverset(Cl)(|)CH-CH3 underset(De...

    Text Solution

    |

  15. X and Y are respectively :

    Text Solution

    |

  16. Identify the major products in the following reactions ? CH3-CH2-und...

    Text Solution

    |

  17. Reaction intermediate of E1cB reaction is :

    Text Solution

    |

  18. In which compund D- exchange is possible in presence of OD^(-) // D(2)...

    Text Solution

    |

  19. Major Product is :

    Text Solution

    |

  20. Major product of given reaction is - O2N-CH2-undersetunderset(Cl)(|)...

    Text Solution

    |