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`CH_3-undersetunderset(CH_3)(|)CH-oversetoverset(Cl)(|)CH-CH_3 underset(Delta)overset(t-BuO) to` Major Product is :

A

`CH_3-undersetunderset(CH_3)(|)C=CH-CH_3`

B

`CH_3-undersetunderset(CH_3)(|)CH-CH=CH_2`

C

`CH_2=undersetunderset(CH_3)(|)C-CH_2-CH_3`

D

`CH_3-undersetunderset(CH_3)(|)CH-oversetoverset(OH)(|)CH-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem, we need to analyze the reaction of the compound with the reagent provided. The compound in question is: \[ CH_3-CH(CH_3)-CH(Cl)-CH_3 \] This compound has a chlorine atom (Cl) attached to a carbon that is also connected to a tertiary carbon (the one with two methyl groups). The reagent used in the reaction is t-butoxide ion (\( t-BuO^- \)), which is a strong base and will promote an elimination reaction. ### Step-by-Step Solution: 1. **Identify the Structure**: The starting compound can be drawn as: \[ CH_3-CH(CH_3)-C(Cl)-CH_3 \] This shows that we have a chlorine atom attached to a secondary carbon. 2. **Determine the Type of Reaction**: The presence of a strong base like t-butoxide indicates that we will likely undergo an elimination reaction (E2 mechanism). The base will abstract a proton (H) from a carbon adjacent to the carbon bearing the chlorine. 3. **Identify Possible Elimination Sites**: The adjacent carbons to the carbon with chlorine are: - One carbon with a hydrogen (from the \( CH \) group) - The other carbon is a tertiary carbon (with two \( CH_3 \) groups). 4. **Elimination Reaction**: The elimination reaction will involve the base abstracting a proton from the adjacent carbon, leading to the formation of a double bond. The most stable alkene is formed by removing a hydrogen from the more substituted carbon. 5. **Forming the Alkene**: By removing a hydrogen from the tertiary carbon (the one with two \( CH_3 \) groups), we can form a double bond with the carbon that has the chlorine. This results in: \[ CH_3-CH(CH_3)=C(CH_3)-CH_3 \] This is a more substituted alkene and is therefore more stable. 6. **Final Product**: The major product of the reaction is: \[ CH_3-CH(CH_3)=C(CH_3)-CH_3 \] This product is 2-methyl-2-butene. ### Conclusion: The major product of the reaction is: \[ \text{2-methyl-2-butene} \]
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RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS-IV-Exercise-1 Part-2
  1. Which of the following reaction is an example of elimination reaction ...

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  2. Correct statement for E1 Reaction is :

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  3. Intermediate formed during E2 reaction is -

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  4. CH3-undersetunderset(CH3)(|)CH-underset(Cl)underset(|)(CH)-CH3 overset...

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  5. CH3-undersetunderset(OH)(|)oversetoverset(CH3)(|)C-CH3 undersetDeltaov...

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  6. In the given reaction : overset(Conc. H2SO4)to [X] as major produ...

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  7. Identify the major formed in the following reaction

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  8. Which of the following does not represent the correct product?

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  9. Correct statement for E1 Reaction is :

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  10. Intermediate formed during E2 reaction is -

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  11. CH3-undersetunderset(H)(|)oversetoverset(CH3)(|)C-CH2Br underset(Delta...

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  12. Which of the following compounds undergo E2 reaction with maximum rate...

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  13. 2-Chlorobutane on treatment with alcoholic KOH/Delta gives major produ...

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  14. CH3-undersetunderset(CH3)(|)CH-oversetoverset(Cl)(|)CH-CH3 underset(De...

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  15. X and Y are respectively :

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  16. Identify the major products in the following reactions ? CH3-CH2-und...

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  17. Reaction intermediate of E1cB reaction is :

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  18. In which compund D- exchange is possible in presence of OD^(-) // D(2)...

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  19. Major Product is :

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  20. Major product of given reaction is - O2N-CH2-undersetunderset(Cl)(|)...

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