Home
Class 11
CHEMISTRY
Identify the major products in the follo...

Identify the major products in the following reactions ?
`CH_3-CH_2-undersetunderset(" "CH_3)(" "|)oversetoverset(" "CH_3)(" "|)(.^(o+)N)-CH_2-CH_2-CH_3 overset(overset(Theta)(O)H//Delta)to`

A

`CH_3-CH=CH_2`

B

`CH_2=CH_2`

C

`{:(" "CH_(3)),(" |"),(CH_(3)CH_(2)-N-OH),(" "o+"|"),(" "CH_(3)):}`

D

`C_2H_5-OH`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the major products of the given reaction involving a quaternary ammonium salt, we can follow these steps: ### Step 1: Understand the Reaction Type The reaction involves a quaternary ammonium salt being treated with a strong base (OH-) and heat. This is indicative of a reaction known as Hofmann elimination. ### Step 2: Identify the Structure of the Quaternary Ammonium Salt The quaternary ammonium salt is represented as: ``` CH3 | CH3-CH2-N^+(CH3)2 | CH2-CH2-CH3 ``` In this structure, the nitrogen is bonded to four carbon groups, making it a quaternary ammonium salt. ### Step 3: Apply Hofmann Elimination In Hofmann elimination, the quaternary ammonium salt decomposes to form an alkene and a tertiary amine (also known as a telseramine). The elimination occurs at the β-hydrogens adjacent to the nitrogen. ### Step 4: Identify β-Hydrogens In the structure, we can identify the β-hydrogens: - The β-hydrogens are the hydrogens on the carbon atoms adjacent to the nitrogen. - There are two β-hydrogens available for elimination. ### Step 5: Determine Possible Alkenes The elimination can lead to the formation of two possible alkenes: 1. Elimination from the β-hydrogen on the left side (leading to propene). 2. Elimination from the β-hydrogen on the right side (leading to ethylene). ### Step 6: Determine the More Substituted Alkene According to Zaitsev's rule, the more substituted alkene is favored. In this case: - The elimination from the β-hydrogen on the left leads to propene (more substituted). - The elimination from the β-hydrogen on the right leads to ethylene (less substituted). ### Step 7: Write the Major Products The major products of the reaction will be: 1. **Alkene**: Propene (CH2=CH-CH3) 2. **Telsaramine**: The remaining structure after elimination, which will be: ``` CH3-CH2-N(CH3)2 ``` ### Final Products Thus, the major products of the reaction are: - **Propene (CH2=CH-CH3)** - **Telsaramine (CH3-CH2-N(CH3)2)** ### Summary of Major Products: 1. Propene (C3H6) 2. Telsaramine (C5H14N) ---
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise Exercise-1 Part-3|2 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise Exercise-2 Part-1|11 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise APSP PART-3|22 Videos
  • ORGANIC REACTION MECHANISMS - II

    RESONANCE ENGLISH|Exercise APSP Part - 3|22 Videos
  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos

Similar Questions

Explore conceptually related problems

What is the major product that will be formed in the following reaction ? CH_3-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH=CH_2+HCl to

The major product formed in the following reaction is : CH_3CH = CHCH(CH_3)_2 overset(HBr)(to)

The major product formed in the following reaction is CH_3-underset(H)underset(|)overset(CH_3)overset(|)C-CH_2Brunderset(CH_3OH)overset(CH_3O^(-))to

The name of CH_3-undersetunderset(CH_3)(|)oversetoverset(CH_3)(|)C-CH_2-oversetoverset(CH_3)(|)CH-CH_3 is :

CH_3-CH_2-undersetunderset(CH_3)(|)oversetoverset(Cl)(|)C-CH_2-CH_3overset(80% EtOH)to What is/are true about above reaction ?

RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS-IV-Exercise-1 Part-2
  1. Which of the following reaction is an example of elimination reaction ...

    Text Solution

    |

  2. Correct statement for E1 Reaction is :

    Text Solution

    |

  3. Intermediate formed during E2 reaction is -

    Text Solution

    |

  4. CH3-undersetunderset(CH3)(|)CH-underset(Cl)underset(|)(CH)-CH3 overset...

    Text Solution

    |

  5. CH3-undersetunderset(OH)(|)oversetoverset(CH3)(|)C-CH3 undersetDeltaov...

    Text Solution

    |

  6. In the given reaction : overset(Conc. H2SO4)to [X] as major produ...

    Text Solution

    |

  7. Identify the major formed in the following reaction

    Text Solution

    |

  8. Which of the following does not represent the correct product?

    Text Solution

    |

  9. Correct statement for E1 Reaction is :

    Text Solution

    |

  10. Intermediate formed during E2 reaction is -

    Text Solution

    |

  11. CH3-undersetunderset(H)(|)oversetoverset(CH3)(|)C-CH2Br underset(Delta...

    Text Solution

    |

  12. Which of the following compounds undergo E2 reaction with maximum rate...

    Text Solution

    |

  13. 2-Chlorobutane on treatment with alcoholic KOH/Delta gives major produ...

    Text Solution

    |

  14. CH3-undersetunderset(CH3)(|)CH-oversetoverset(Cl)(|)CH-CH3 underset(De...

    Text Solution

    |

  15. X and Y are respectively :

    Text Solution

    |

  16. Identify the major products in the following reactions ? CH3-CH2-und...

    Text Solution

    |

  17. Reaction intermediate of E1cB reaction is :

    Text Solution

    |

  18. In which compund D- exchange is possible in presence of OD^(-) // D(2)...

    Text Solution

    |

  19. Major Product is :

    Text Solution

    |

  20. Major product of given reaction is - O2N-CH2-undersetunderset(Cl)(|)...

    Text Solution

    |