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Major product of given reaction is - O...

Major product of given reaction is -
`O_2N-CH_2-undersetunderset(Cl)(|)CH-CH_3overset(overset(Theta)(O)H)underset(Delta)to` Major product

A

`O_2N-CH=CH-CH_3`

B

`O_2N-CH_2-CH=CH_2`

C

`O_2N-CH=undersetunderset(Cl)(|)C-CH_3`

D

`CH_2=undersetunderset(NO_2)(|)C-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the given reaction, let's analyze the process step by step. ### Step 1: Identify the Reactant Structure The reactant is `O_2N-CH_2-CHCl-CH_3`. This compound contains a nitro group (-NO2), a chloro group (-Cl), and a methyl group (-CH3) attached to a carbon chain. ### Step 2: Assess the Acidity of the Hydrogen The hydrogen atom attached to the carbon adjacent to the nitro and chloro groups is more acidic due to the electron-withdrawing effects of these groups. The nitro group is a strong electron-withdrawing group, which stabilizes the negative charge that will form when a hydrogen is removed. ### Step 3: Deprotonation by OH- When the compound is treated with hydroxide ions (OH-), it will abstract the acidic hydrogen from the carbon adjacent to the nitro and chloro groups. This results in the formation of a carbanion. ### Step 4: Resonance Stabilization of the Carbanion The carbanion formed is stabilized by resonance. The negative charge can be delocalized over the adjacent carbon atoms due to the presence of the nitro group. The resonance structures can be represented as: - O2N-CH=CH-CH3 - O2N-CH2-CH(-)CH3 This resonance stabilization makes the carbanion more stable. ### Step 5: Elimination of Chloride Ion The next step involves the elimination of the chloride ion (Cl-). The presence of the carbanion allows for the formation of a double bond between the two carbon atoms adjacent to the nitro group. The elimination of Cl- leads to the formation of a double bond. ### Step 6: Final Product Formation After the elimination of Cl-, the final product can be represented as: `O_2N-CH=CH-CH_3` ### Conclusion The major product of the reaction is: `O_2N-CH=CH-CH_3`
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RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS-IV-Exercise-1 Part-2
  1. Which of the following reaction is an example of elimination reaction ...

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  2. Correct statement for E1 Reaction is :

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  3. Intermediate formed during E2 reaction is -

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  4. CH3-undersetunderset(CH3)(|)CH-underset(Cl)underset(|)(CH)-CH3 overset...

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  5. CH3-undersetunderset(OH)(|)oversetoverset(CH3)(|)C-CH3 undersetDeltaov...

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  6. In the given reaction : overset(Conc. H2SO4)to [X] as major produ...

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  7. Identify the major formed in the following reaction

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  8. Which of the following does not represent the correct product?

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  9. Correct statement for E1 Reaction is :

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  10. Intermediate formed during E2 reaction is -

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  11. CH3-undersetunderset(H)(|)oversetoverset(CH3)(|)C-CH2Br underset(Delta...

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  12. Which of the following compounds undergo E2 reaction with maximum rate...

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  13. 2-Chlorobutane on treatment with alcoholic KOH/Delta gives major produ...

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  14. CH3-undersetunderset(CH3)(|)CH-oversetoverset(Cl)(|)CH-CH3 underset(De...

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  15. X and Y are respectively :

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  16. Identify the major products in the following reactions ? CH3-CH2-und...

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  17. Reaction intermediate of E1cB reaction is :

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  18. In which compund D- exchange is possible in presence of OD^(-) // D(2)...

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  19. Major Product is :

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  20. Major product of given reaction is - O2N-CH2-undersetunderset(Cl)(|)...

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