Home
Class 11
CHEMISTRY
Compound X on treatment with HI give Y, ...

Compound X on treatment with HI give Y, Y on treatment with ethanolic KOH gives Z (an isomer of X). Ozonolysis of Z (with `H_2O_2` workup) gives a two -carbon carboxylic acid and four carbon ketone . Hence, X is :

A

2-methyl-2-pentene

B

4-methyl-1-pentene

C

2,3-dimethyl-2-butene

D

3-methyl-1-pentene

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to analyze the information given in the question and derive the structure of compound X. ### Step 1: Analyze the reaction with HI - Compound X reacts with HI to give compound Y. This indicates that X is likely an alkene since HI adds across the double bond. - The addition of HI follows Markovnikov's rule, meaning that the hydrogen atom from HI will attach to the carbon with more hydrogen substituents, while the iodine will attach to the other carbon. ### Step 2: Determine the structure of Y - The product Y is formed from the addition of HI to X. Since we do not have the structure of X yet, we cannot directly draw Y. However, we know that Y will be a haloalkane. ### Step 3: Analyze the reaction with ethanolic KOH - Y is treated with ethanolic KOH, leading to the formation of Z, which is an isomer of X. The reaction with KOH suggests that a dehydrohalogenation occurs, resulting in the formation of a double bond. - Since Z is an isomer of X, it must have the same molecular formula but a different structural arrangement. ### Step 4: Ozonolysis of Z - The ozonolysis of Z with a hydrogen peroxide workup yields a two-carbon carboxylic acid and a four-carbon ketone. - The two-carbon carboxylic acid is likely acetic acid (CH₃COOH), and the four-carbon ketone could be butanone (CH₃COCH₂CH₃). ### Step 5: Deduce the structure of Z - The ozonolysis products suggest that Z must have a structure that, when cleaved, produces these specific fragments. - The presence of a two-carbon carboxylic acid and a four-carbon ketone indicates that Z could be a 5-carbon alkene. ### Step 6: Identify the structure of X - Since Z is an isomer of X, we can deduce the structure of X based on the possible structures of Z. - If Z is an alkene that can yield a two-carbon acid and a four-carbon ketone upon ozonolysis, we can hypothesize that Z could be 3-methyl-1-pentene (C₅H₁₀). - Therefore, X must be 3-methyl-1-pentene, which upon treatment with HI gives a haloalkane (Y), and then dehydrohalogenation with KOH gives Z. ### Final Answer Thus, the compound X is **3-methyl-1-pentene**. ---
Promotional Banner

Topper's Solved these Questions

  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise APSP PART-3|22 Videos
  • ORGANIC REACTION MECHANISMS-IV

    RESONANCE ENGLISH|Exercise APSP PART-1|30 Videos
  • ORGANIC REACTION MECHANISMS - II

    RESONANCE ENGLISH|Exercise APSP Part - 3|22 Videos
  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(BASIC CONCEPTS)|27 Videos

Similar Questions

Explore conceptually related problems

H_(2)O_(2) on treatment with chlorine gives:

Oxalic acid on treatment with conc. H_(2) SO_(4) gives

The compound which gives H_2O_2 on treatment with dilute acid is

The oxide that gives H_(2)O_(2) on treatment with a dilute sulfuric acid is

Compound (X) C_(6)H_(5)O gives yellow coloured ppt with 2,4 DNP but does not give red colored ppt with Fehiling's solution (X) on treatement with NH_(2)OH H^(+) gives compound (Y) C_(6)H_(5)NO (Y) when treated with PCl_(5) gives isomeric compound (Z) . (Z) on hydrolysis gives propanoic acid and aniline. what will be the correct structure of (X) ,(Y) and (Z) ?

A metal X on heating in nitrogen gas gives Y,Y on treatment with H_(2)O gives a colourless gas which when passed through CuSO_(4) solution gives a blue colour. Y is:

A metal X on heating in nitrogen gas gives Y,Y on treatment with H_(2)O gives a colourless gas which when passed through chloroplatinic acid produces yellow precipitate 'Y' is :

Bromobenzene on treatment with fuming H_(2)SO_(4) gives a compound which one treatment with Cl_(2)//AlCl_(3) gives (A), (A) on distillation with dil. H_(2)SO_(4) gives (B). (B) on treatment with an eq. of Mg in dry ether gives (C ). (C ) on treatment with CH_(3)CHO followed by hydrolysis gives (D). (D) on treatment with NaOl gives (E). Identify the structures of (A) to (E).