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An alkyl halide (X) on reaction with eth...

An alkyl halide (X) on reaction with ethanolic sodium hydroxide forms an alkene (Y) which on further reaction with HBr gives the same alkyl halide.The alkene (Y) on reaction with HBr/ peroxide followed by reaction with Mg metal followed by reaction with HCN produces an aldehyde (Z).Z is :

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to analyze the reactions described in the question. ### Step 1: Identify the Alkyl Halide (X) Let’s assume the alkyl halide (X) is a simple alkyl halide, such as bromoethane (C2H5Br). ### Step 2: Reaction with Ethanolic Sodium Hydroxide When alkyl halide (X) reacts with ethanolic sodium hydroxide (NaOH), it undergoes an elimination reaction (dehydrohalogenation) to form an alkene (Y). - For example, bromoethane (C2H5Br) reacts with NaOH to form ethene (C2H4). **Reaction:** C2H5Br + NaOH (ethanol) → C2H4 (Y) + NaBr + H2O ### Step 3: Reaction of Alkene (Y) with HBr The alkene (Y) then reacts with HBr to give back the same alkyl halide (X). - In our case, ethene (C2H4) reacts with HBr to form bromoethane (C2H5Br). **Reaction:** C2H4 (Y) + HBr → C2H5Br (X) ### Step 4: Reaction of Alkene (Y) with HBr in Presence of Peroxide Now, if the alkene (Y) reacts with HBr in the presence of peroxide, it follows the anti-Markovnikov addition rule, leading to the formation of a bromoalkane where bromine adds to the less substituted carbon. - For ethene, this step is not applicable as it is symmetrical, but if we consider a more complex alkene, the product would be different. **Example Reaction:** C2H4 + HBr (in presence of peroxide) → C2H5Br (still the same for symmetrical alkenes) ### Step 5: Reaction with Magnesium Metal The product from the previous step (bromoalkane) reacts with magnesium metal to form a Grignard reagent. - For example, C2H5Br + Mg → C2H5MgBr ### Step 6: Reaction with HCN The Grignard reagent (C2H5MgBr) then reacts with HCN to form an intermediate that eventually leads to the formation of an aldehyde (Z). - The reaction with HCN introduces a cyanide group, and upon hydrolysis, it will convert to an aldehyde. **Final Reaction:** C2H5MgBr + HCN → C2H5-CN (intermediate) → C2H5CHO (aldehyde Z) ### Conclusion The final product (aldehyde Z) is **ethyl aldehyde (acetaldehyde)**, which is represented as CH3CHO. ### Final Answer: **Z is: Acetaldehyde (CH3CHO)** ---
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