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CH2Ounderset(H3O^(o+))overset(CHD2MgI)to...

`CH_2Ounderset(H_3O^(o+))overset(CHD_2MgI)toX underset(Delta)overset(Conc.H_2SO_4)toY`
In the above reaction compound X & Y respectively will be

A

`oversetoverset(OH)(|)CHD-CH_2-OH,CHO-CHO`

B

`CHD_2-CH_2-OH, CHO-CHO`

C

`CHD_2-CH_2-OH, CD_2=CH_2`

D

`undersetunderset(OH)(|)CHD-CH_2-OH,CD_2=CD_2`

Text Solution

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The correct Answer is:
To solve the given reaction step by step, let's analyze the transformation of formaldehyde (CH₂O) through the Grignard reagent (CHD₂MgI) and then through concentrated sulfuric acid. ### Step 1: Reaction of Formaldehyde with Grignard Reagent 1. **Identify the Reactants**: The starting compound is formaldehyde (CH₂O) and the Grignard reagent is CHD₂MgI. 2. **Nucleophilic Attack**: The nucleophile (CHD₂⁻) from the Grignard reagent attacks the electrophilic carbon of the carbonyl group (C=O) in formaldehyde. This results in the breaking of the double bond and the formation of an alkoxide intermediate. - **Intermediate Structure**: The structure after the nucleophilic attack will be: - O⁻ (alkoxide) attached to the carbon, which is also attached to a hydrogen (H) and a CHD₂ group. 3. **Formation of Alkoxide**: The alkoxide (O⁻) will then react with the magnesium ion (MgI⁺) from the Grignard reagent, leading to the formation of: - CH₂(OH)CHD₂MgI ### Step 2: Protonation of the Alkoxide 1. **Reaction with Acid**: The alkoxide (CH₂(OH)CHD₂⁻) is then treated with H₃O⁺ (acid), which protonates the oxygen atom. 2. **Final Product (X)**: After protonation, the product will be: - CH₂(OH)CHD₂ - This compound is an alcohol where the OH group is attached to the carbon that was originally part of the carbonyl group of formaldehyde. ### Step 3: Dehydration with Concentrated Sulfuric Acid 1. **Reaction with Concentrated H₂SO₄**: The alcohol (CH₂(OH)CHD₂) is treated with concentrated sulfuric acid (H₂SO₄) and heated. This is a dehydration reaction where water (H₂O) is eliminated. 2. **Formation of Alkene (Y)**: The elimination of water leads to the formation of a double bond between the two carbon atoms: - The resulting product will be: - CH₂=CHD₂ - This compound is an alkene. ### Summary of Products - **Compound X**: CH₂(OH)CHD₂ (an alcohol) - **Compound Y**: CH₂=CHD₂ (an alkene) ### Final Answer - The compounds X and Y are: - **X**: CH₂(OH)CHD₂ - **Y**: CH₂=CHD₂

To solve the given reaction step by step, let's analyze the transformation of formaldehyde (CH₂O) through the Grignard reagent (CHD₂MgI) and then through concentrated sulfuric acid. ### Step 1: Reaction of Formaldehyde with Grignard Reagent 1. **Identify the Reactants**: The starting compound is formaldehyde (CH₂O) and the Grignard reagent is CHD₂MgI. 2. **Nucleophilic Attack**: The nucleophile (CHD₂⁻) from the Grignard reagent attacks the electrophilic carbon of the carbonyl group (C=O) in formaldehyde. This results in the breaking of the double bond and the formation of an alkoxide intermediate. - **Intermediate Structure**: The structure after the nucleophilic attack will be: - O⁻ (alkoxide) attached to the carbon, which is also attached to a hydrogen (H) and a CHD₂ group. 3. **Formation of Alkoxide**: The alkoxide (O⁻) will then react with the magnesium ion (MgI⁺) from the Grignard reagent, leading to the formation of: ...
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RESONANCE ENGLISH-ORGANIC REACTION MECHANISMS-IV-APSP PART-3
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