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R-C-=N underset(-40^(@)C)overset(DIBAL+H...

`R-C-=N underset(-40^(@)C)overset(DIBAL+H,H_(@)O)rarr` Product
The product formed is :

A

`R-CO-NH_(2)`

B

`R-CH_(2)-NH_(2)`

C

`R-CHO`

D

`R-CH_(2)-NO_(2)`

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The correct Answer is:
To solve the question regarding the reaction of the compound \( R-C \equiv N \) (a nitrile) with DIBAL-H and water at -40°C, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant:** The reactant is a nitrile, represented as \( R-C \equiv N \). This structure indicates that there is a carbon atom (C) triple-bonded to a nitrogen atom (N), with an alkyl group (R) attached to the carbon. 2. **Understand the Reagent:** The reagent used in the reaction is DIBAL-H, which stands for diisobutylaluminium hydride. DIBAL-H is a selective reducing agent that is commonly used to reduce nitriles to aldehydes. 3. **Reaction Conditions:** The reaction is performed at a low temperature of -40°C. This low temperature is crucial as it helps in controlling the reaction, ensuring that the nitrile is converted to an aldehyde without further reduction to an alcohol. 4. **Reduction Mechanism:** When the nitrile \( R-C \equiv N \) is treated with DIBAL-H, the triple bond between carbon and nitrogen is reduced. The nitrogen atom is converted to a less oxidized state, while the carbon atom that was part of the nitrile becomes part of an aldehyde functional group. 5. **Hydrolysis:** After the reduction step, the reaction mixture is hydrolyzed with water (H2O). This step is necessary to convert the intermediate formed during the reduction into the final aldehyde product. 6. **Final Product:** The final product of this reaction is an aldehyde, represented as \( RCHO \). The structure indicates that the carbon atom from the nitrile has now formed a double bond with an oxygen atom (C=O), characteristic of aldehydes, while the number of carbon atoms remains the same. ### Conclusion: The product formed from the reaction of \( R-C \equiv N \) with DIBAL-H and water at -40°C is \( RCHO \) (an aldehyde).
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