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which of the compound give iodoform whe...

which of the compound give iodoform when react with `IO^(-)` (hypoiodite)

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To determine which compounds give a positive iodoform test when reacted with hypoiodite (IO⁻), we need to identify the structural features that allow for this reaction. The iodoform test is a qualitative test for the presence of a methyl ketone (R-CO-CH₃) or a secondary alcohol that can be oxidized to a methyl ketone. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: - The iodoform test is positive for compounds that have a methyl group adjacent to a carbonyl group (C=O) or a secondary alcohol that can be converted to a methyl ketone. - The specific structure we are looking for is CH₃CO- (a methyl ketone) or R-CHOH-CH₃ (a secondary alcohol). 2. **List Possible Compounds**: - Consider the compounds that might be tested. Common examples include: - Ethanol (CH₃CH₂OH) - Acetone (CH₃COCH₃) - Butan-2-ol (CH₃CHOHCH₂CH₃) - Propan-2-ol (CH₃CHOHCH₃) - Ethyl methyl ketone (CH₃C(O)CH₂CH₃) 3. **Analyze Each Compound**: - **Ethanol (CH₃CH₂OH)**: Does not have a methyl ketone structure, so it will not give a positive test. - **Acetone (CH₃COCH₃)**: Has a methyl ketone structure, so it will give a positive iodoform test. - **Butan-2-ol (CH₃CHOHCH₂CH₃)**: Can be oxidized to a methyl ketone (CH₃COCH₃), so it will give a positive test. - **Propan-2-ol (CH₃CHOHCH₃)**: Can also be oxidized to a methyl ketone (CH₃COCH₃), so it will give a positive test. - **Ethyl methyl ketone (CH₃C(O)CH₂CH₃)**: Contains a methyl ketone structure, so it will give a positive test. 4. **Conclusion**: - The compounds that give a positive iodoform test when reacted with hypoiodite (IO⁻) are: - Acetone (CH₃COCH₃) - Butan-2-ol (CH₃CHOHCH₂CH₃) - Propan-2-ol (CH₃CHOHCH₃) - Ethyl methyl ketone (CH₃C(O)CH₂CH₃) ### Final Answer: - The compounds that give a positive iodoform test are Acetone, Butan-2-ol, Propan-2-ol, and Ethyl methyl ketone.

To determine which compounds give a positive iodoform test when reacted with hypoiodite (IO⁻), we need to identify the structural features that allow for this reaction. The iodoform test is a qualitative test for the presence of a methyl ketone (R-CO-CH₃) or a secondary alcohol that can be oxidized to a methyl ketone. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: - The iodoform test is positive for compounds that have a methyl group adjacent to a carbonyl group (C=O) or a secondary alcohol that can be converted to a methyl ketone. - The specific structure we are looking for is CH₃CO- (a methyl ketone) or R-CHOH-CH₃ (a secondary alcohol). ...
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RESONANCE ENGLISH-STRUCTURAL IDENTIFICATION & PRACTICAL ORGANIC CHEMISTRY-APSP
  1. Which of the following compounds will give a positive iodoform test ?

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  2. The following two compounds I and II can be distinguished by using rea...

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  3. which of the compound give iodoform when react with IO^(-) (hypoiodit...

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  4. How many structural isomeric ketones having molecular formula (C(5)H(1...

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  5. Which of the structural isomeric ketones having molecular formula (C(5...

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  6. can be distinguish by

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  7. (x) C(7)H(12)underset(Me(2)S)overset(O(3))rarrP+Q Compound P respond...

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  8. Total number of monochloro structure products

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  9. Yellow precipitate obtained during the test of halogen by lassaigne's...

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  10. A research scholar get a mixture of three product during an experiment...

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  11. How many alcohols give immediate turbidity with Lucas reagent having m...

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  12. Which of the following compound can give test with Tollen's reagent an...

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  13. Which is incorrect match with respect to the reagent used for lab test...

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  14. How many hydrocarbons having molecular mass 68 can give white precipit...

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  15. On oxidative ozonolysis of 3-Methylhex-3-ene, two products A & B are f...

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  16. can be differentiated by

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  17. Test to differentiate between ethanol (CH(3)CH(2)OH) and phenol (Ph-OH...

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  18. Which of the following compounds gives azo dye test ?

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  19. A compound (P) , obtained as an ozonolysis product of (Q) gives brisk ...

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  20. Which of the following reagent can distinguish the given compound I an...

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