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The lattice of CaF(2) is called fluorite...

The lattice of `CaF_(2)` is called fluorite structure. `SrCl_(2)` has fluorite structure. Which of the following statements is true for `SrCl_(2)` ?

A

`Sr^(2+)` are at the corner and face centres of the cubic arrangment

B

`Sr^(2+)` are arranged in bcc lattice

C

`a^(-)` are arranged in fcc lattice

D

`Cl^(-)` occupy octahedral holes in the lattice

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The correct Answer is:
To determine which statement is true for the structure of \( \text{SrCl}_2 \) (which has a fluorite structure similar to \( \text{CaF}_2 \)), we can analyze the arrangement of ions in the lattice. ### Step-by-Step Solution: 1. **Understanding the Fluorite Structure**: - The fluorite structure is characterized by a face-centered cubic (FCC) arrangement of cations with anions occupying the tetrahedral holes. In the case of \( \text{CaF}_2 \), calcium ions (\( \text{Ca}^{2+} \)) are at the corners and face centers of the cubic unit cell, while fluoride ions (\( \text{F}^- \)) occupy the tetrahedral sites. 2. **Identifying the Ions in \( \text{SrCl}_2 \)**: - In \( \text{SrCl}_2 \), strontium ions (\( \text{Sr}^{2+} \)) play a similar role to calcium ions in \( \text{CaF}_2 \), while chloride ions (\( \text{Cl}^- \)) will occupy the tetrahedral holes in the FCC lattice formed by the strontium ions. 3. **Analyzing the Statements**: - **Statement 1**: \( \text{Sr}^{2+} \) ions are at the corners and face centers of the cubic arrangement. - This statement is **true** because in the fluorite structure, the cations are indeed located at these positions. - **Statement 2**: \( \text{Sr}^{2+} \) ions are arranged in a BCC lattice. - This statement is **false**. The cations are arranged in an FCC lattice. - **Statement 3**: \( \text{Cl}^- \) ions are arranged in an FCC lattice. - This statement is **false**. The \( \text{Cl}^- \) ions occupy the tetrahedral holes in the FCC lattice formed by \( \text{Sr}^{2+} \) ions, not in an FCC lattice themselves. - **Statement 4**: \( \text{Cl}^- \) ions occupy octahedral holes in the lattice. - This statement is **false**. In the fluorite structure, \( \text{Cl}^- \) ions occupy tetrahedral holes, not octahedral holes. 4. **Conclusion**: - The only true statement regarding the structure of \( \text{SrCl}_2 \) is **Statement 1**: \( \text{Sr}^{2+} \) ions are at the corners and face centers of the cubic arrangement. ### Final Answer: The true statement for \( \text{SrCl}_2 \) is that \( \text{Sr}^{2+} \) ions are at the corners and face centers of the cubic arrangement.

To determine which statement is true for the structure of \( \text{SrCl}_2 \) (which has a fluorite structure similar to \( \text{CaF}_2 \)), we can analyze the arrangement of ions in the lattice. ### Step-by-Step Solution: 1. **Understanding the Fluorite Structure**: - The fluorite structure is characterized by a face-centered cubic (FCC) arrangement of cations with anions occupying the tetrahedral holes. In the case of \( \text{CaF}_2 \), calcium ions (\( \text{Ca}^{2+} \)) are at the corners and face centers of the cubic unit cell, while fluoride ions (\( \text{F}^- \)) occupy the tetrahedral sites. 2. **Identifying the Ions in \( \text{SrCl}_2 \)**: ...
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