Home
Class 12
CHEMISTRY
Among the complex ions, [Co(NH(2) - C...

Among the complex ions,
`[Co(NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) Cl_(2)]^(+), [CrCl_(2) (C_(2)O_(4))_(2)]^(3-)`
`[Fe(H_(2)O)_(4) (OH)_(2)]^(+), [Fe(NH_(3))_(2) (CN)_(4)]^(-)`,
`[Co (NH_(2) - CH_(2) - CH_(2) - NH_(2))_(2) (NH_(3)) Cl]^(2+)` and
that show(s) cis-trans isomerism is

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given complex ions show cis-trans isomerism, we will analyze each complex based on its structure and ligand arrangement. ### Step-by-Step Solution: 1. **Identify the Complex Ions**: We have the following complex ions: - `[Co(NH2-CH2-CH2-NH2)2Cl2]^(+)` - `[CrCl2(C2O4)2]^(3-)` - `[Fe(H2O)4(OH)2]^(+)` - `[Fe(NH3)2(CN)4]^(-)` - `[Co(NH2-CH2-CH2-NH2)2(NH3)Cl]^(2+)` 2. **Analyze the First Complex**: - **Complex**: `[Co(NH2-CH2-CH2-NH2)2Cl2]^(+)` - **Type**: This is a MA2B2 type complex (where A is the bidentate ligand ethylenediamine (en) and B is the monodentate ligand Cl). - **Isomerism**: This complex can exhibit both cis and trans isomerism due to the arrangement of the bidentate ligands. 3. **Analyze the Second Complex**: - **Complex**: `[CrCl2(C2O4)2]^(3-)` - **Type**: This is also a MA2B2 type complex (where A is the bidentate ligand oxalate (C2O4) and B is Cl). - **Isomerism**: This complex can also exhibit cis and trans isomerism. 4. **Analyze the Third Complex**: - **Complex**: `[Fe(H2O)4(OH)2]^(+)` - **Type**: This is an MA4B2 type complex (where A is H2O and B is OH). - **Isomerism**: This complex can show cis and trans isomerism as well. 5. **Analyze the Fourth Complex**: - **Complex**: `[Fe(NH3)2(CN)4]^-` - **Type**: This is also an MA4B2 type complex (where A is NH3 and B is CN). - **Isomerism**: This complex can exhibit cis and trans isomerism. 6. **Analyze the Fifth Complex**: - **Complex**: `[Co(NH2-CH2-CH2-NH2)2(NH3)Cl]^(2+)` - **Type**: This is a MA2BC type complex (where A is the bidentate ligand ethylenediamine, B is NH3, and C is Cl). - **Isomerism**: This complex can also show cis and trans isomerism. ### Conclusion: All five complex ions can exhibit cis-trans isomerism due to their respective ligand arrangements. ### Final Answer: All the given complex ions show cis-trans isomerism.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    RESONANCE ENGLISH|Exercise Exercise-3 Part-I: JEE(Advance ) /IIT-JEE Problem (Comprehenion )|1 Videos
  • COORDINATION COMPOUNDS

    RESONANCE ENGLISH|Exercise Exercise-3 Part-II: JEE(Main ) /AIEEE Problem|36 Videos
  • COORDINATION COMPOUNDS

    RESONANCE ENGLISH|Exercise Exercise-2 Part-IV: Comprehension -4|1 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Chemistry in every day life)|31 Videos
  • D & F BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Aldehydes , Ketones, Carboxylic acid)|15 Videos

Similar Questions

Explore conceptually related problems

Write IUPAC name of CH_(3)-CH_(2)-NH_(2)

Among the following optical activity is possible in (a) [Co(H_(2)O)_(2)(NH_(3))_(3)CI]^(o+) (b) [Co(H_(2)O))_(4)CI_(2)]^(o+)] (c ) [Co(NH_(3))_(4)(NO_(2))CI]^(o+) (d) [Co(CN)_(5)NC]^(Θ) .

The IUPAC name of the complex ion [CoCl(NH_3)(NH_2CH_2CH_2NH_2)_2]^(2+) is:

IUPAC name of CH_(2)=CH-CH_(2)NH_(2) is :

NH_(4)OH , NaOH, CH_(3)COOH , H_(2)S

~[NH (CH_(2))_(6) NHCO (CH_(2))_(4) CO]~ is a

The common name of the compounds CH_(2)=CH-CH_(2)-NH_(2) is

The relationship between [Co(NH_(2)-CH_(2)-underset(CH)underset(|)(CH)-CH_(2)-NH_(2))_(2)Cl_(2)]^(+) and [Co(NH_(2)-CH_(2)-CH_(2)-CH_(2)-NH_(2)]_(2)Cl_(2)]^(+) is

The denticity of the ligand N(CH_(2)CH_(2)NH_(2))_(3) is

Which is the correct order of increasing basicity? (A) CH_(3) CH_(2) CH_(3) (B) CH_(3) CH_(2) CH_(3) (C) CH_(3) CH_(2) NH_(2) (D) CH_(3) CH_(2) CH_(3) < CH_(3) CH_(2)OH < CH_(3) CH_(2)NH_(2) < CH_(3) CH_(2) SH

RESONANCE ENGLISH-COORDINATION COMPOUNDS-Exercise-3 Part-I: JEE(Advance ) /IIT-JEE Problem
  1. The volume (in mL) of 0.1 M AgNO(3) for complete precipitation of chlo...

    Text Solution

    |

  2. As per IUPAC nomenclature, the name of the complex, [Co(H2O)4(NH3)2]Cl...

    Text Solution

    |

  3. [NiCl(2){P(C(2)H(5))(2)(C(6)H(5))}(2)] exhibits temperature dependent ...

    Text Solution

    |

  4. Consider the follwing complexes ion P,Q and R P =[FeF(6)]^(3-), Q=[V...

    Text Solution

    |

  5. The pair of coordination complex exhibiting the same kind of isomerism...

    Text Solution

    |

  6. EDTA^(4-) i9s ethylenediamine tetraacetate ion The total number of N-C...

    Text Solution

    |

  7. A list of species having the formula of XZ(4) is given below XeF(4), S...

    Text Solution

    |

  8. Match each coordination compounds in List-I with an appropriate pair o...

    Text Solution

    |

  9. For the octahedral complexes of Fe^(3+) in SCN^(-) (thiocyanato - S) a...

    Text Solution

    |

  10. In the complex acetylbromidodicarbonylbis (triethylphosphine) iron (II...

    Text Solution

    |

  11. Among the complex ions, [Co(NH(2) - CH(2) - CH(2) - NH(2))(2) Cl(2)...

    Text Solution

    |

  12. Among [Ni(CO)(4)], [NiCl(4)]^(2-), [Co(NH(3))(4)Cl(2)]Cl, Na(3)[CoF(6)...

    Text Solution

    |

  13. The number of geometric isomers possible for the complex [CoL(2)Cl(2)]...

    Text Solution

    |

  14. The geometries of the ammonia complexes of Ni^(2+),Pt^(2+) and Zn^(2+)...

    Text Solution

    |

  15. Addition of excess aqueous ammonia to a pink coloured aqueous solution...

    Text Solution

    |

  16. The correct statement (s) regarding the binary transition metal carbon...

    Text Solution

    |

  17. Among the species given below, the total number of diamagnetic species...

    Text Solution

    |

  18. Ammonia prepared by treating ammonium sulphate with calcium hydroxide ...

    Text Solution

    |

  19. The correct option(s) regarding the complex [Co(en)(NH(3))(3)(H(2)O)](...

    Text Solution

    |

  20. Match each set of hybrid orbitals from LIST–I with complex(es) given i...

    Text Solution

    |