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Addition of excess aqueous ammonia to a ...

Addition of excess aqueous ammonia to a pink coloured aqueous solution of `MCl_(2). 6H_(2)O(X) and NH_(4)Cl` gives an octahedral complex Y in the presence of air. In aqueous solution, complex Y behaves as 1:3 electrolyte. The reaction of X with excess HCl at room temperature results in the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M., whereas it is zero for complex Y.
Among the following options, which statement is incorrect ?

A

The hybridization of the central metal ion in Y is `d^(2)sp^(3)`

B

Addition of silver nitrate of Y gives only tow equivalents of silver chloride

C

When X and Z in equilibrium at `0^(@)C`, the colour of the solution is pink

D

Z is a tetrahedral complex.

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The correct Answer is:
A, C, D
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