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Among the species given below, the total...

Among the species given below, the total number of diamagnetic species is _________. H atom, `NO_(2)` monomer,`O_(2)^(-)` (superoxide), dimeric sulphur in vapour phase,
`Mn_(3)O_(4),(NH_(4))_(2)["FeCl"_(4)], (NH_(4))_(2)["NiCl"_(4)],K_(2)MnO_(4), K_(2)CrO_(4)`

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To determine the total number of diamagnetic species among the given options, we will analyze each species one by one, focusing on their electronic configurations and the presence of unpaired electrons. ### Step-by-Step Solution: 1. **H atom**: - The hydrogen atom has one electron (1s¹). - Since it has one unpaired electron, it is **paramagnetic**. 2. **NO₂ (monomer)**: - The nitrogen dioxide molecule has an odd number of electrons (11 total). - It has unpaired electrons, making it **paramagnetic**. 3. **O₂⁻ (superoxide)**: - The superoxide ion has 17 electrons (16 from O₂ and 1 extra). - It has unpaired electrons, so it is **paramagnetic**. 4. **Dimeric sulfur in vapor phase**: - Dimeric sulfur (S₂) has 16 electrons. - The electronic configuration shows that it has unpaired electrons, thus it is **paramagnetic**. 5. **Mn₃O₄**: - The oxidation states of manganese in Mn₃O₄ are +2 and +3. - In both oxidation states, there are unpaired electrons, making it **paramagnetic**. 6. **(NH₄)₂[FeCl₄]**: - The oxidation state of iron in this complex is +2. - The electronic configuration of Fe²⁺ (3d⁶) shows unpaired electrons, so it is **paramagnetic**. 7. **(NH₄)₂[NiCl₄]**: - The oxidation state of nickel in this complex is +2. - The electronic configuration of Ni²⁺ (3d⁸) shows unpaired electrons, making it **paramagnetic**. 8. **K₂MnO₄**: - The oxidation state of manganese in K₂MnO₄ is +6. - The electronic configuration of Mn⁶⁺ (3d¹) shows one unpaired electron, so it is **paramagnetic**. 9. **K₂CrO₄**: - The oxidation state of chromium in K₂CrO₄ is +6. - The electronic configuration of Cr⁶⁺ (3d⁰) shows no unpaired electrons, making it **diamagnetic**. ### Summary of Results: - **Diamagnetic Species**: K₂CrO₄ (1 species) - **Paramagnetic Species**: H atom, NO₂, O₂⁻, dimeric sulfur, Mn₃O₄, (NH₄)₂[FeCl₄], (NH₄)₂[NiCl₄], K₂MnO₄ (8 species) ### Total Number of Diamagnetic Species: The total number of diamagnetic species is **1**. ---
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