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Name of the type of isomerism exhibited ...

Name of the type of isomerism exhibited by the following pairs of compounds :
`[Co(NH_(3))_(6) [Cr(CN)_(6)] and [Cr(NH_(3))_(6)] [Co(CN)_(6)]`

A

Ionization

B

Linkage

C

Coordination

D

Polymerization.

Text Solution

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The correct Answer is:
C
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how will you distinguish between the following pairs of isomers [Cr(NH_(3))_(3)(NO_(2))_(3)] and [Cr(NH_(3))_(6)][Cr(NO_(2))_(6)]

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coordination compounds often show various types of isomerism. The isomerism can be categorized in two main types (a) structural isomerism (b) stereo or space isomerism Structural isomerism arises due to the difference in structures of coordination-sempounds while stereo or space isomerism arises on account of the different positions and arrangements of ligands (atoms or groups) in space around the metal lonStructural isomerism can be classified in following types (i) tonization isomers- which give different ions in solution, e.g. [CoBr(NH_(3))_(5)]]SO_(4) and [Co(SO_(4))_(5)(NH_(3))_(5)]Br Hydrate isomers which differ in H_(2)O as ligand or as hydration, e.g. [Cr(H_(2)O)_(5)]CI_(2)(H_(2)O)]Cl_(2).H_(2)O[CrCl_(2)(H_(2)O)]CI.2H_(2)O (iii) Linkage isomers, which differ in atom linked to 'metal atom, e.g. [CO(NO_(2))(NH_(3))_(5)]^(2+) and CO(ONO)(NH_(3))_(6)]^(2+) Coordination isomers- which involve interchange of ligands, e.g. [Co(NH_(3))_(6)] [Cr(CN)_(6)] and [Cr(NH_(3))_(6)] [Co(CN)_(6)] (v) Coordination position isomerism-which arises in the bridged complexes due to the difference in the attachment of ligands with the metal atoms QThe compounds [Cr(H_(2)O_(6)]Cl_(3)[Cr(H_(2)O)_(5)CI]Cl_(2).H_(2)O and [Cr(H_(2)O)_(4)Cl_(2)]Cl2H_(2)O exhibit

RESONANCE ENGLISH-COORDINATION COMPOUNDS-Additional Problem for Self Practice (APSP) Part-II
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  2. dsp^(2) hybridization represent

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  3. Name of the type of isomerism exhibited by the following pairs of com...

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  4. The complex pentaaminecarbonatocobalt(III) chlorides is :

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  5. According to the Crystal Field Theory, the energy of d(xy) orbital is ...

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  6. The orbitals of iron involved in the hybridization in Fe(CO)(5) are

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  7. The crystal field stabilization energy (CFSE) in [Co(SCN)(6)]^(3-) is ...

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  8. How many isomers are possible for a compound with formula, [Co(en)(2)C...

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  9. Metal carbonyls have the metal ions in zero or unusually lower oxidati...

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  10. Among the following, the chiral complex is :

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  11. The species having tetrahedral shape is:

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  12. Which kind of isomerism is exhibited by octahedral [Co(NH(3))(2)Br(2)]...

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  13. Write the formula of tetraamminedichloridochromium(III) chloride.

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  14. The coordination number and magnetic moment of the complex [Cr(C(2)O(4...

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  15. The comopound which exhibits coordination isomerism is:

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  16. The strong field ligand is "

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  17. The correct formula for hexaaminecobalt(III) nitrate is

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  18. The IUPAC name of complex [Cu(en)(2)(H(2)O)(2)]^(2+)

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  19. The electronic spectrum of [Ti(H(2)O)(6)]^(3+) shows a single broad pe...

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  20. Dimethyl glyoxime forms a square planar complex with Ni^(2+) . This co...

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