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The IUPAC name for K(2)[Cr(CN)(2)O(2)(O)...

The IUPAC name for `K_(2)[Cr(CN)_(2)O_(2)(O)_(2)NH_(3)]` is:

A

potassium amminecyanoperoxodioxochromatic(V)

B

potassium amminedicyanoperoxodioxochromium(VI)

C

potassium amminecyanoperoxodioxochromium (VI)

D

potassium amminedicyanodioxoperoxochromate (VI

Text Solution

Verified by Experts

The correct Answer is:
D

`2K^(+)[Cr overset(-2)((CN)_(2))overset(-2)(O_(2)) overset(-4)((O)_(2))(overset(0)(NH_(3)))]^(2-)`
Oxidation state of chromium `=x+2(-1)+(-2)+2(-2)+(0)=-2`.
`:. X=+6`.
As per IUPAC name.
Complex is anionic, so metal ion will be named as chromate with +6 oxidation state. So, potassium amminedicyanodioxoperoxochromate(VI).
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RESONANCE ENGLISH-COORDINATION COMPOUNDS-Additional Problem for Self Practice (APSP) Part-III Only one option correct type
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