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Tetrahedral complexes are generally favo...

Tetrahedral complexes are generally favoured:

A

where the ligands are bulky

B

when the ligands are stronger

C

where the electronic configuration of the central metal is `d^(0) d^(5) or d^(10)` (with weak field ligands ) as there is no CFSE.

D

when the central metal ion has pseudo noble gas electron configuration ,i.e,(n-1)`d^(10)ns^(0)np^(0)`

Text Solution

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The correct Answer is:
To solve the question regarding the conditions under which tetrahedral complexes are generally favored, we will analyze each of the provided options step by step. ### Step-by-Step Solution: 1. **Understanding Tetrahedral Complexes**: - Tetrahedral complexes are coordination compounds where the central metal atom is surrounded by ligands at the corners of a tetrahedron. The geometry is typically favored under certain conditions related to the nature of the ligands and the electronic configuration of the central metal. 2. **Analyzing Option 1**: - **Statement**: Tetrahedral complexes are favored by large ligands. - **Explanation**: It is known that tetrahedral complexes are generally favored by larger ligands (such as Cl⁻, Br⁻) because they can fit better in the tetrahedral arrangement due to steric factors. - **Conclusion**: This option is **correct**. 3. **Analyzing Option 2**: - **Statement**: Tetrahedral complexes are favored when the ligands are stronger. - **Explanation**: Strong field ligands tend to cause a larger splitting of d-orbitals, which typically leads to octahedral complexes rather than tetrahedral. Tetrahedral complexes are favored by weak field ligands. - **Conclusion**: This option is **incorrect**. 4. **Analyzing Option 3**: - **Statement**: Tetrahedral complexes are favored when the electronic configuration of the central metal is D0, D5, or D10 with weak field ligands. - **Explanation**: In tetrahedral complexes, weak field ligands do not cause significant splitting of the d-orbitals, which is consistent with the configurations mentioned (D0, D5, D10). Thus, this condition supports the formation of tetrahedral complexes. - **Conclusion**: This option is **correct**. 5. **Analyzing Option 4**: - **Statement**: Tetrahedral complexes are favored when the central metal ion has a pseudo noble gas electron configuration (N-1)D10, NS0, NP0. - **Explanation**: Transition metals with a pseudo noble gas configuration (which implies a filled d-subshell) often form stable tetrahedral complexes, particularly when paired with weak field ligands. - **Conclusion**: This option is **correct**. ### Final Answer: Based on the analysis: - **Correct Options**: Option 1, Option 3, and Option 4.

To solve the question regarding the conditions under which tetrahedral complexes are generally favored, we will analyze each of the provided options step by step. ### Step-by-Step Solution: 1. **Understanding Tetrahedral Complexes**: - Tetrahedral complexes are coordination compounds where the central metal atom is surrounded by ligands at the corners of a tetrahedron. The geometry is typically favored under certain conditions related to the nature of the ligands and the electronic configuration of the central metal. 2. **Analyzing Option 1**: ...
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