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Magnetic moment of a compound of vanadiu...

Magnetic moment of a compound of vanadium is 1.73 BM. Write the number of unpaired electron and the electronic configuration of Vanadium in this compound .

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To solve the problem, we need to determine the number of unpaired electrons and the electronic configuration of vanadium in a compound where its magnetic moment is given as 1.73 BM (Bohr Magneton). ### Step-by-Step Solution: 1. **Understand the Magnetic Moment Formula**: The magnetic moment (μ) can be calculated using the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. 2. **Set Up the Equation**: Given that the magnetic moment is 1.73 BM, we can set up the equation: \[ 1.73 = \sqrt{n(n + 2)} \] 3. **Square Both Sides**: To eliminate the square root, square both sides of the equation: \[ (1.73)^2 = n(n + 2) \] This simplifies to: \[ 2.9929 = n(n + 2) \] 4. **Rearrange the Equation**: Rearranging gives us a quadratic equation: \[ n^2 + 2n - 2.9929 = 0 \] 5. **Solve the Quadratic Equation**: We can use the quadratic formula \( n = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a} \) where \( a = 1, b = 2, c = -2.9929 \): \[ n = \frac{-2 \pm \sqrt{(2)^2 - 4 \cdot 1 \cdot (-2.9929)}}{2 \cdot 1} \] \[ n = \frac{-2 \pm \sqrt{4 + 11.9716}}{2} \] \[ n = \frac{-2 \pm \sqrt{15.9716}}{2} \] \[ n = \frac{-2 \pm 3.99}{2} \] This gives two possible values for \( n \): \[ n \approx 0.995 \quad \text{(not valid, as n must be a whole number)} \] \[ n \approx 1 \quad \text{(valid)} \] 6. **Determine the Electronic Configuration of Vanadium**: Vanadium (V) has an atomic number of 23. The ground state electronic configuration of vanadium is: \[ \text{V: } 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^2 \, 3d^3 \] 7. **Determine the Oxidation State**: Since we found that \( n = 1 \), this indicates that in the compound, vanadium must lose electrons to have only one unpaired electron. The oxidation state of vanadium in this compound is +4 (V^4+). 8. **Electronic Configuration of V^4+**: When vanadium is in the +4 oxidation state, it loses 4 electrons (2 from 4s and 2 from 3d): \[ \text{V}^{4+}: 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^0 \, 3d^1 \] In this configuration, there is 1 unpaired electron in the 3d orbital. ### Final Answers: - **Number of unpaired electrons**: 1 - **Electronic configuration of vanadium in this compound**: \( 1s^2 \, 2s^2 \, 2p^6 \, 3s^2 \, 3p^6 \, 4s^0 \, 3d^1 \)
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