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H(2)C(2)O(4) and NaHC(2)O(4) behave as a...

`H_(2)C_(2)O_(4)` and `NaHC_(2)O_(4)` behave as acids as well as reducing agents. Which of the following are correct statements?

A

equivalent weight of `H_(2)C_(2)O_(4)` and `NaHC_(2)O_(4)` are equal to their molecular weights when behaving as reducing agents.

B

100 ml of 1 (N) solution of each is neutralised by equal volume of 1 (M)` Ca(OH)_(2)`

C

100 ml of (N) solution `H_(2)C_(2)O_(4)` is neutralised by equal volumes of 1 (N) `Ca(OH)_(2)`

D

100 ml of (M) solution of each is oxidised by same volume of 1 (M) `KMnO_(4)`

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The correct Answer is:
C, D
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H_(2)C_(2)O_(4) acts as an acid as well as an oxidizing agent. The correct statement (s) about H_(2)C_(2)O_(4) is /are .

H_2O_2 cannot act as reducing agent. True or False

A mixture of H_(2)C_(2)O_(4) and NaHC_(2)O_(4) weighing 2.02 g was dissolved in water and the solution made uptp one litre. 10 mL of this solution required 3.0 mL of 0.1 N NaOH solution for complete neutralization. In another experiment 10 mL of same solution in hot dilute H_(2)SO_(4) medium required 4 mL of 0.1N KMnO_(4) KMnO_(4) for compltete neutralization. Calculate the amount of H_(2)C_(2)O_(4) and NaHC_(2)O_(4) in mixture.

A mixture of H_(2)C_(2)O_(4) and NaHC_(2)O_(4) weighing 2.02 g was dissolved in water and the solution made upto one litre. 10 mL of this solution required 3.0 mL of 0.1 N NaOH solution for complete neutralization. In another experiment 10 mL of same solution in hot dilute H_(2)SO_(4) medium required 4 mL of 0.1N KMnO_(4) for complete neutralization. Calculate the amount of H_(2)C_(2)O_(4) and NaHC_(2)O_(4) in mixture.

In acidic medium , H_(2)O_(2) acts as a reducing agent in its reaction with :

The strength of H_(2)O_(2) is expressed in several ways like molarity, normality,% (w/V), volume strength, etc. The strength of "10 V" means 1 volume of H_(2)O_(2) on decomposition gives 10 volumes of oxygen at 1 atm and 273 K or 1 litre of H_(2)O_(2) gives 10 litre of O_(2) at 1 atm and 273 K The decomposition of H_(2)O_(2) is shown as under : H_(2)O_(2)(aq) to H_(2)O(l)+(1)/(2)O_(2)(g) H_(2)O_(2) can acts as oxidising as well as reducing agent. As oxidizing agent H_(2)O_(2) is converted into H_(2)O and as reducing agent H_(2)O_(2) is converted into O_(2) . For both cases its n-factor is 2. :. "Normality " "of" H_(2)O_(2) "solution" =2xx "molarity of" H_(2)O_(2) solution 20mL of H_(2)O_(2) solution is reacted with 80 mL of 0.05 MKMnO_(4) "in acidic medium then what is the volume strength of" H_(2)O_(2) ?

The strength of H_(2)O_(2) is expressed in several ways like molarity, normality,% (w/V), volume strength, etc. The strength of "10 V" means 1 volume of H_(2)O_(2) on decomposition gives 10 volumes of oxygen at 1 atm and 273 K or 1 litre of H_(2)O_(2) gives 10 litre of O_(2) at 1 atm and 273 K The decomposition of H_(2)O_(2) is shown as under : H_(2)O_(2)(aq) to H_(2)O(l)+(1)/(2)O_(2)(g) H_(2)O_(2) can acts as oxidising as well as reducing agent. As oxidizing agent H_(2)O_(2) is converted into H_(2)O and as reducing agent H_(2)O_(2) is converted into O_(2) . For both cases its n-factor is 2. :. "Normality " "of" H_(2)O_(2) " solution " =2xx "molarity of" H_(2)O_(2) solution 40 g Ba(MnO_(4))_(2) (mol.mass=375) sample containing some inert impurities in acidic medium completely reacts with 125 mL of "33.6 V" of H_(2)O_(2) . What is the percentage purity of the sample ?

RESONANCE ENGLISH-EQUIVALENT CONCEPT & TITRATIONS-Part -IV
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