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Consider the reactions shown below : ...

Consider the reactions shown below :

Which of the follwoing statements is false?

A

Silver chromate (VI) has the formula `Ag_(2)CrO_(4)`.

B

The minimum mass of zinc required to reduce 0.1 mole of `Cr^(3+)` to `Cr^(2+)` is 6.54g.

C

The conversion of `CrO_(4)^(2-)` into `Cr_(2)O_(7)^(2-)` is not a redox reaction.

D

The equation `Cr_(2)O_(7)^(2-) + 14H^(+)+6Fe^(2+)rarr2Cr^(3+)+7H_(2)O` correctly describes the reduction of `Cr_(2)O_(7)^(2-)` by acidified `FeSO_(4)`.

Text Solution

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The correct Answer is:
A, C, D

(A) Formula of silver chromate (VI) will be `Ag_(2)CrO_(4)`
(B) Minimum mass of zinc required for reduction of 0.1 mole of `Cr^(3+)` to `Cr^(2+)=(0.1)/(2)` moles of Zn
(v.f. of Zn = 2 & v.f. of `Cr^(3+)=1`) `" " (6.54)/(2)g=3.27g`
(c) `CrO_(4)^(2-)hArrCr_(2)O_(7)^(2-)`
in both ions, chromium is in +6 oxidation state.
(D) Given reaction is correct.
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RESONANCE ENGLISH-EQUIVALENT CONCEPT & TITRATIONS-Part -IV
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  2. 20mL of H(2)O(2) after acidification with dilute H(2)SO(4) required 30...

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  3. As(2)S(3) is

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  4. During the titration of a mixture of Na(2)CO(3) and NaHCO(3) against H...

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  5. In the reaction CrO(5) + H(2)SO(4)rarr Cr(2)(sO(4))(3)+H(2)O+O(2), one...

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  6. Consider the redox reaction 2S(2)O(3)^(2-)+I(2)rarrS(4)O(6)^(2-)+2I^...

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  7. Which of the following relations is/are correct for solutions ?

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  8. Which of the following statements is/are correct

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  9. H(2)C(2)O(4) and NaHC(2)O(4) behave as acids as well as reducing agent...

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  10. Consider the reactions shown below : Which of the follwoing state...

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