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Cholesterol, when isolated from natural ...

Cholesterol, when isolated from natural sources, is obtained as a single enantiomer. The observed rotation `alpha` of a 0.3 g sample of cholesterol in 5mL of chloroform solution contained in a 10 cm polarimeter tube is `-0.78^(@)`. Calculate the specific rotation of cholesterol. A sample of synthetic cholesterol was prepared consisting entirely of (+)-cholesterol. This synthetic (+)-cholesterol was mixed with some natural (-)-cholesterol. The mixture had a specific rotation `[alpha]_(D)^(20) " of " -13^(@).` What fraction of the mixture was (+)-cholesterol ?

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To solve the problem step by step, we will first calculate the specific rotation of cholesterol and then determine the fraction of the mixture that was (+)-cholesterol. ### Step 1: Calculate the Specific Rotation of Cholesterol The formula for specific rotation \([α]\) is given by: \[ [α] = \frac{α}{l \cdot c} ...
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RESONANCE ENGLISH-STEREOISOMERISM-EXERCISE (PART III : PRACTICE TEST-2 (IIT-JEE (ADVANCED PATTERN))
  1. Cholesterol, when isolated from natural sources, is obtained as a sing...

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  2. is a Fischer projection of one of stereoisomers ?

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  3. Which of the following has maximum number of two-fold axis of symmetry...

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  4. The following compounds are :

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  5. Which conformation of Bicyclo [2, 2, 2]-octane is more stable?

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  6. In the given energy graph for cyclohexane, the point "B" represent.

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  7. Identify the most stable stereoisomer :

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  8. Molecular formula of smallest ester which contain one chiral carbon is...

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  9. Correct the following names : 2-ol-2, 3-dimethylbutane

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  10. Which statement(s) is/are correct for the given reaction and compounds...

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  11. Intra-molecular H-bonding is possible in which of the following.

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  12. Which of the following statement(s) is/are correct ?

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  13. Which of the following compounds can show Optical isomerism as well as...

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  14. Which of the following compound will show geometrical isomerism?

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  15. Which of the following statement(s) is/are true about the following co...

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  16. An organic compound P exists in two enantiomeric forms, which have spe...

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  17. Total number of meso forms possible for 1,2,3,4 -Tetrachlorocyclobutan...

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  18. If "A" is total number of meso compounds and "B" is total number of op...

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  19. Sum of total no. of stereoisomers (A) and total no. of fractions (B) f...

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  20. Which of the following carbonyl compound will give two products after ...

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  21. Total number of stereoisomers of truxillic acid are :

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