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Total number of optical active stereoiso...

Total number of optical active stereoisomers of the following compound is :
`CH_(3)-CH=CH-CHOH-CH=CH-CH_(3)`

A

8

B

6

C

4

D

2

Text Solution

AI Generated Solution

The correct Answer is:
To determine the total number of optical active stereoisomers for the compound `CH3-CH=CH-CHOH-CH=CH-CH3`, we will follow these steps: ### Step 1: Identify the Structure The given compound is `CH3-CH=CH-CHOH-CH=CH-CH3`. This compound has two double bonds and a hydroxyl group (-OH). ### Step 2: Count the Chiral Centers A chiral center (or chiral carbon) is a carbon atom that is attached to four different groups. We need to analyze the structure to identify any chiral centers. - The first carbon (C1) is attached to two hydrogens and a methyl group (CH3), so it is not chiral. - The second carbon (C2) is part of a double bond and is attached to two hydrogens, so it is not chiral. - The third carbon (C3) is part of a double bond and is attached to a hydrogen and a hydroxyl group, but it also has another carbon attached, making it not chiral. - The fourth carbon (C4) has a hydroxyl group and is attached to two other carbons, but it is not chiral as it has two identical groups (the two adjacent carbons). - The fifth carbon (C5) is part of a double bond and is attached to two hydrogens, so it is not chiral. - The sixth carbon (C6) is attached to two hydrogens and a methyl group, so it is not chiral. After analyzing all the carbons, we find that there are **no chiral centers** in this compound. ### Step 3: Count the Double Bonds The compound has **two double bonds**. ### Step 4: Apply the Formula for Stereoisomers The formula for calculating the number of stereoisomers is given by: \[ \text{Number of stereoisomers} = 2^{(n + c)} \] where: - \( n \) = number of double bonds - \( c \) = number of chiral centers In our case: - \( n = 2 \) (from the two double bonds) - \( c = 0 \) (since there are no chiral centers) Thus, substituting the values: \[ \text{Number of stereoisomers} = 2^{(2 + 0)} = 2^2 = 4 \] ### Conclusion The total number of optical active stereoisomers for the compound `CH3-CH=CH-CHOH-CH=CH-CH3` is **4**. ---
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