Home
Class 12
CHEMISTRY
The most stable form of meso-tartaric ac...

The most stable form of meso-tartaric acid is

A

Gauche form

B

Anti form

C

Fully eclipsed form

D

Partially eclipsed

Text Solution

AI Generated Solution

The correct Answer is:
To determine the most stable form of meso-tartaric acid, we need to analyze its structure and the concept of stability in stereoisomers. Here's a step-by-step solution: ### Step 1: Understand the Structure of Tartaric Acid Tartaric acid has two carboxylic acid groups (-COOH) and two hydroxyl groups (-OH) attached to a four-carbon chain. The general structure can be represented as: ``` HOOC | CH | CH | COOH ``` ### Step 2: Identify Meso Compounds A meso compound is one that has multiple stereocenters but is superimposable on its mirror image due to an internal plane of symmetry. Meso-tartaric acid has two stereocenters, and due to its symmetrical structure, it is classified as a meso compound. ### Step 3: Analyze the Conformations Tartaric acid can exist in different conformations. The two main conformations are: - **Anti-form**: where the hydroxyl groups are positioned opposite to each other. - **Syn-form**: where the hydroxyl groups are positioned adjacent to each other. ### Step 4: Determine Stability Factors The stability of these conformations can be influenced by steric hindrance and intramolecular interactions: - **Anti-form**: This conformation minimizes steric hindrance between the bulky -OH and -COOH groups. Additionally, it allows for potential hydrogen bonding between the hydroxyl groups, which can enhance stability. - **Syn-form**: This conformation experiences steric hindrance due to the proximity of the hydroxyl groups, making it less stable. ### Step 5: Conclusion Given that the anti-form of meso-tartaric acid has reduced steric hindrance and the possibility of hydrogen bonding, it is the most stable form of meso-tartaric acid. ### Final Answer The most stable form of meso-tartaric acid is the **anti-form**. ---

To determine the most stable form of meso-tartaric acid, we need to analyze its structure and the concept of stability in stereoisomers. Here's a step-by-step solution: ### Step 1: Understand the Structure of Tartaric Acid Tartaric acid has two carboxylic acid groups (-COOH) and two hydroxyl groups (-OH) attached to a four-carbon chain. The general structure can be represented as: ``` HOOC | ...
Promotional Banner

Topper's Solved these Questions

  • STEREOISOMERISM

    RESONANCE ENGLISH|Exercise EXERCISE (PART II : NATIONAL STANDARD EXAMINATION IN CHEMISTRY (NSEC) STAGE-1)|55 Videos
  • STEREOISOMERISM

    RESONANCE ENGLISH|Exercise EXERCISE (PART III : PRACTICE TEST-2 (IIT-JEE (ADVANCED PATTERN))|23 Videos
  • STEREOISOMERISM

    RESONANCE ENGLISH|Exercise EXERCISE (PART -II ONLINE JEE MAIN)|3 Videos
  • SOLUTIONS

    RESONANCE ENGLISH|Exercise Advabced Level Problems (PART-2)|35 Videos
  • STRUCTURAL IDENTIFICATION

    RESONANCE ENGLISH|Exercise Advanced level Problems (Part-III)|12 Videos

Similar Questions

Explore conceptually related problems

The most stable ion is .

The most stable ion is:

Find the most stable form

The net optical rotation of meso-tartaric acid is ......... due to ........ compensation.

Thermodynamically the most stable form of carbon is

The most stable anion is:

The most stable complex ion is :-

Why is the net rotation of meso-tartaric acid zero ?

What is the enthalpy of formation of the most stable form of an element in its standard state ?

RESONANCE ENGLISH-STEREOISOMERISM-EXERCISE (ADDITIONAL PROBLEMS FOR SELF PRACTICE (APSP)) PART 1
  1. How many position isomers are possible of trichlorocyclohexane which c...

    Text Solution

    |

  2. The total number of stereoisomers of 2, 3-pentanediol are

    Text Solution

    |

  3. The most stable form of meso-tartaric acid is

    Text Solution

    |

  4. Which of the following molecules possess a plane of symmetry ?

    Text Solution

    |

  5. Select correct order of stability of different forms of 1-Chloro-4-iod...

    Text Solution

    |

  6. Which of the following statement is incorrect ?

    Text Solution

    |

  7. Which type of isomerism is shown by 2, 3-Dichlorobutane ?

    Text Solution

    |

  8. Increasing order of stability among the three main conformation ( i.e....

    Text Solution

    |

  9. The unusually stable three membered unsaturated compound, Feist acid w...

    Text Solution

    |

  10. Which of the following depict the same ?

    Text Solution

    |

  11. The total number of chiral centres present in the artificial sweetener...

    Text Solution

    |

  12. Which pair is identical ?

    Text Solution

    |

  13. Identify the relation between molecules given in Newman and Fischer pr...

    Text Solution

    |

  14. The correct IUPAC name of D-Glucose is :

    Text Solution

    |

  15. Which of the following species will be optically active ?

    Text Solution

    |

  16. Which of the following compounds exhibits stereoisomerism?

    Text Solution

    |

  17. The isomeric alcohol which has a chiral carbon atom is :1

    Text Solution

    |

  18. Which of the following are intensive properties?

    Text Solution

    |

  19. The R/S designation for the following stereoisomers of 1,3-dichloro-2-...

    Text Solution

    |

  20. Which of the following will not show geometrical isomerism?

    Text Solution

    |