Home
Class 12
CHEMISTRY
The following symmetry element is presen...

The following symmetry element is present in the 'd' as will as the 'l' form of Tartaric acid
`[CO_(2)HCH(OH) CH(OH)CO_(2)H]`

A

centre of symmetry

B

axis of symmetry `(C_(2))`

C

plane of symmetry

D

None

Text Solution

AI Generated Solution

The correct Answer is:
To determine the symmetry element present in both the D and L forms of tartaric acid, we will follow these steps: ### Step 1: Draw the Structures of D and L Tartaric Acid - **D Tartaric Acid**: The structure can be represented as: ``` COOH | C(OH) | C(OH) | COOH ``` Here, the two hydroxyl (OH) groups are on the same side of the central carbon chain. - **L Tartaric Acid**: The structure is similar but with the hydroxyl groups on the opposite sides: ``` COOH | C(OH) | C(OH) | COOH ``` In this case, the two hydroxyl (OH) groups are on opposite sides of the central carbon chain. ### Step 2: Analyze the Symmetry Elements - **Plane of Symmetry**: Check if there is a plane that divides the molecule into two mirror-image halves. In both D and L forms, there is no plane of symmetry due to the arrangement of the functional groups. - **Center of Symmetry**: Check if there is a point in the molecule from which identical parts are found in opposite directions. Both forms do not have a center of symmetry. ### Step 3: Identify the Axis of Symmetry - **C2 Axis of Symmetry**: - If we consider an axis that runs vertically through the central carbon atoms, we can rotate the molecule 180 degrees around this axis. - Upon rotation, the positions of the hydroxyl (OH) groups and carboxylic acid (COOH) groups will interchange, resulting in the same molecule. ### Conclusion Both the D and L forms of tartaric acid possess a **C2 axis of symmetry**. This means that if you rotate the molecule 180 degrees about this axis, you will obtain the same structure. ### Summary of the Solution: 1. Draw the structures of D and L tartaric acid. 2. Analyze the presence of symmetry elements: no plane or center of symmetry. 3. Identify the C2 axis of symmetry present in both forms.
Promotional Banner

Topper's Solved these Questions

  • STEREOISOMERISM

    RESONANCE ENGLISH|Exercise EXERCISE (PART III : PRACTICE TEST-2 (IIT-JEE (ADVANCED PATTERN))|23 Videos
  • STEREOISOMERISM

    RESONANCE ENGLISH|Exercise EXERCISE (ADDITIONAL PROBLEMS FOR SELF PRACTICE (APSP)) PART 1|30 Videos
  • SOLUTIONS

    RESONANCE ENGLISH|Exercise Advabced Level Problems (PART-2)|35 Videos
  • STRUCTURAL IDENTIFICATION

    RESONANCE ENGLISH|Exercise Advanced level Problems (Part-III)|12 Videos

Similar Questions

Explore conceptually related problems

Which of the following would you predict to be the stronger acid? (a) Benzoic acid or para-nitrobenzoic acid (b) CH_(3)-CH_(2)-CH_(2)-OH or CH_(3)-CH=CH-OH (c) CH_(3)-CH=CH-CH_(2)-OH or CH_(3)-CH=CH-OH .

Which out of the following is : ( a) the weakest acid (b) the strongest acid ? (i) C_(2)H_(5)OH (ii) CH_(3)COOH (iii) C_(6)H_(5)OH (iv) H_(2)O

IUPAC name of CH_(2)OH-CH_(2)OH is

Arrange the following in decreasing order of acidic nature of (a) (i) F_(3) C C H_(2) OH , (ii) (CH_(3))_(3) C C H_(2) OH , (iii) FCH_(2) CH_(2) C_(2) OH (b)

Give the IUPAC name of the compound CH_3-CH(OH)-CO-CH_2-CH_3

Arrange the following in order of decreasing acid strength: CH_(3)OH, H_(2)O, C_(6)H_(5)OH

Arrange the following acid in decreasing order of their acidic strength : (I) CH_(3)-OH (II) CH_(3)CH_(2)-OH (III) CH_(3)-underset(CH_(3))underset(|)(CH)-OH (IV) CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-OH

CH_(3)OH , CH_(4), NaOH , C_(2)H_(5)OH

RESONANCE ENGLISH-STEREOISOMERISM-EXERCISE (PART II : NATIONAL STANDARD EXAMINATION IN CHEMISTRY (NSEC) STAGE-1)
  1. The achiral species among the following is :

    Text Solution

    |

  2. Which one of the following compounds has (Z) configuration about the C...

    Text Solution

    |

  3. The following symmetry element is present in the 'd' as will as the 'l...

    Text Solution

    |

  4. Conformational changes in ethane molecule leads the change in:

    Text Solution

    |

  5. How many chiral carbon atoms does Tetrachycline A (a broad spectrum an...

    Text Solution

    |

  6. How many sterioisomers does the following compound have ? CH(3)-CH(...

    Text Solution

    |

  7. For cyclohexane, which of the following factors does not make the boat...

    Text Solution

    |

  8. The following molecule has a

    Text Solution

    |

  9. The absolute confirgurations of the chiral centres 1,2 and 5 in the fo...

    Text Solution

    |

  10. The following structures are

    Text Solution

    |

  11. The isomeric alcohol which has a chiral carbon atom is :

    Text Solution

    |

  12. Geometrical isomerism results because molecule has

    Text Solution

    |

  13. What are enantiomers

    Text Solution

    |

  14. The number of all types of isomers of chlorobutane is :

    Text Solution

    |

  15. (i) CH(2)=CH-CH(2)-CH=CH(2) (ii) CH(2)=CH-CH=CH-CH(3) (iii) CH(3)-...

    Text Solution

    |

  16. The configurations of the carbon atoms C(2) and C(3) in the following ...

    Text Solution

    |

  17. The compound that is chiral

    Text Solution

    |

  18. The number of stereoisomers of compound CH(3)-CH=CH-CH(Br)CH(3) is :

    Text Solution

    |

  19. The R/S designation for the following stereoisomers of 1,3-Dibromo-2-m...

    Text Solution

    |

  20. Among the isomers of Dimethylcyclohexanes, the chiral ones are

    Text Solution

    |