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The number of stereoisomers of compound ...

The number of stereoisomers of compound `CH_(3)-CH=CH-CH(Br)CH_(3)` is :

A

2

B

3

C

4

D

6

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The correct Answer is:
To determine the number of stereoisomers for the compound \( CH_3-CH=CH-CH(Br)CH_3 \), we will follow these steps: ### Step 1: Identify the structure of the compound The compound can be represented as follows: - The first carbon (C1) is attached to three hydrogens and one carbon (C2). - The second carbon (C2) is attached to one hydrogen, one carbon (C3), and one carbon (C1) with a double bond. - The third carbon (C3) is attached to one hydrogen, one carbon (C4), and one carbon (C2) with a double bond. - The fourth carbon (C4) is attached to one bromine atom, one carbon (C5), and one hydrogen. - The fifth carbon (C5) is attached to three hydrogens and one carbon (C4). ### Step 2: Count the number of chiral centers A chiral carbon atom is defined as a carbon atom that is bonded to four different groups. - C1: Has three hydrogens and one carbon (not chiral). - C2: Has one hydrogen, one carbon (C1), and one carbon (C3) (not chiral due to the double bond). - C3: Has one hydrogen, one carbon (C2), and one carbon (C4) (not chiral due to the double bond). - C4: Has one bromine, one hydrogen, and one carbon (C5) (this is a chiral center). - C5: Has three hydrogens and one carbon (not chiral). Thus, there is **one chiral carbon atom** (C4). ### Step 3: Count the number of double bonds In the compound, there is **one double bond** between C2 and C3. ### Step 4: Calculate the total number of stereoisomers The formula for calculating the number of stereoisomers is given by: \[ \text{Number of stereoisomers} = 2^{(n)} \] where \( n \) is the sum of the number of chiral centers and the number of double bonds. Here, we have: - Number of chiral centers = 1 (from C4) - Number of double bonds = 1 (between C2 and C3) Thus, \( n = 1 + 1 = 2 \). Now, substituting into the formula: \[ \text{Number of stereoisomers} = 2^2 = 4 \] ### Conclusion The number of stereoisomers for the compound \( CH_3-CH=CH-CH(Br)CH_3 \) is **4**. ---
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RESONANCE ENGLISH-STEREOISOMERISM-EXERCISE (PART II : NATIONAL STANDARD EXAMINATION IN CHEMISTRY (NSEC) STAGE-1)
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