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For H(3)PO(3) and H(3)PO(4) the correc...

For ` H_(3)PO_(3) and H_(3)PO_(4)` the correct choice is

A

`H_(3)PO_(3)` is dibasic and reducing

B

`H_(3)PO_(3)` is dibasic and non-reducing

C

`H_(3)PO_(4)` is tribasic and reducing

D

`H_(3)PO_(3)` is tribasic and non-reducing

Text Solution

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The correct Answer is:
A
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H_(3)PO_(2),H_(3)PO_(3) and H_(3)PO_(4) which of them are tribasic acids

We have a 0.1M solution of NH_(2)CONH_(2),H_(3)PO_(3) and H_(3)PO_(4) then which of the following statement is correct, if we consider 100% dissociation for H_(3)PO_(3) and H_(3)PO_(4)

Assertion: H_(3)PO_(4) and H_(3)PO_(3) both are present in fertilizers. Reason: H_(3)PO_(3) increases the solubility of fertilizers.

State true or false : The geometry of phosphorus in H_(3)PO_(2),H_(3)PO_(3) and H_(3)PO_(4) is tetrahedral

Ionistable H atom in H_(3)PO_(3) is x and in H_(3)PO_(2) is y. Then ratio of x:y is

1 mol of H_(3)PO_(2), H_(3)PO_(3) and H_(3)PO_(4) will neutralise x mol NaOH , y mol of Ca(OH)_(2) and z mol of Al(OH)_(3) respectively (assuming all as strong electrolytes). x, y, z are in the ratio of:

Assertion (A): There is very little difference in acid strength of H_(3)PO_(4), H_(3)PO_(3) ,and H_(3)PO_(2) . Reason (R) : The hydrogens in these acids are not all bonded to oxygens. The electrone-grativities of P and H are almost the same.

For, H_(3)PO_(4)+H_(2)OhArrH_(3)O^(+)+H_(2)PO_(4)^(-), K_(a_(1)) H_(2)PO_(4)+H_(2)OhArrH_(3)O^(+)+HPO_(4)^(2-), K_(a_(2)) HPO_(4)^(2-)+H_(2)OhArrH_(3)O^(+)+PO_(4)^(3-), K_(a_(3)) The correct order of K_(a) values is:

Statement-1: HBr can be obtained by treating NaBr with H_(3)PO_(4) . Statement-2: H_(3)PO_(4) is stronger acid than HBr.

The true statement for the acids of phosphorus, H_(3)PO_(2), H_(3)PO_(3) and H_(3)PO_(4) is

RESONANCE ENGLISH-NITROGEN & OXYGEN FAMILY-Exercise 3 (Part-I: JEE Advanced)
  1. Nitrogen exists as diatomic molecule and phosphorus as P(4). Why?

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  2. Polyphosphates llike sodium hexametaphosphate (calgon) are used as wat...

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  3. For H(3)PO(3) and H(3)PO(4) the correct choice is

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  4. (NH4)2Cr2O7 on heating gives a gas which is also given by

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  5. A pale bule liquid is obtained by equuimolar mixture of two gases at -...

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  6. Thermodynamically most stable allotrope of phosphorus is :

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  7. How many grams of CaO are required to neutralise 852 g of P4 O10 ? Dra...

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  8. There are some deposits of nitrated and phosphates in the earth's crus...

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  9. There are some deposits of nitrated and phosphates in the earth's crus...

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  10. There are some deposits of nitrates and phosphates in the earth's crus...

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  11. The reaction of P4 with X leads selectively to P4 O6. X is

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  12. Match each of the reaction given in Column I with the corresponding pr...

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  13. Extra pure N2 can be obtained by heating

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  14. Among the following, the number of compounds that can react with PCl(5...

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  15. Which of the following sequence of compounds is according to the decre...

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  16. Concentrated HNO3, upon long standing, turns yellow-brown due to the f...

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  17. The pair(s) of reagents that yield paramagnetic species is/are

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  18. The product formed in the reaction of SOCl2 (thionyl chloride) with wh...

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  19. The compound (s) which generate (s) N(2) upon thermal decomposation is...

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  20. Which of the following compounds release reddish brown gas on heating?

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