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There are some deposits of nitrated and ...

There are some deposits of nitrated and phosphates in the earth's crust. Nitrates are more soluble in water. Nitrates are difficult to reduce under laboratory conditions but microbes do it easily. Ammonia forms a large number of complexes with transition metal ions. Hybridisation easily explains the ease of sigma donation capability of `NH_3` and `PH_3`. Phosphine is a flammable gas and is prepared from white phosphorous.
Which of the following statement is correct ?

A

between `NH_(3) and PH_(3), NH_(3)` is a better electron donor because the lone pair of electrons occupies spherical 's' orbital and is less directional

B

between `NH_(3) and PH_(3), PH_(3)` is a better electron donor because the lone pair of electrons occupies `sp^(3)` orbital and is more directional

C

between `NH_(3) and PH_(3), NH_(3)` is a better electron donor because the lone pair of electrons occupies `sp^(3)` orbital and is more directional

D

between `NH_(3) and PH_(3), PH_(3)` is a better electron donor because the lone pair of electrons occupies spherical 's' orbital and is less directional

Text Solution

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The correct Answer is:
C
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There are some deposits of nitrated and phosphates in the earth's crust. Nitrates are more soluble in water. Nitrates are difficult to reduce under laboratory conditions but microbes do it easily. Ammonia forms a large number of complexes with transition metal ions. Hybridisation easily explains the ease of sigma donation capability of NH_3 and PH_3 . Phosphine is a flammable gas and is prepared from white phosphorous. White phosphorous on reaction with NaOH gives PH_3 as one of the products. This is a.

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RESONANCE ENGLISH-NITROGEN & OXYGEN FAMILY-Exercise 3 (Part-I: JEE Advanced)
  1. How many grams of CaO are required to neutralise 852 g of P4 O10 ? Dra...

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  2. There are some deposits of nitrated and phosphates in the earth's crus...

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  3. There are some deposits of nitrated and phosphates in the earth's crus...

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  4. There are some deposits of nitrates and phosphates in the earth's crus...

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  5. The reaction of P4 with X leads selectively to P4 O6. X is

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  6. Match each of the reaction given in Column I with the corresponding pr...

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  7. Extra pure N2 can be obtained by heating

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  8. Among the following, the number of compounds that can react with PCl(5...

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  9. Which of the following sequence of compounds is according to the decre...

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  10. Concentrated HNO3, upon long standing, turns yellow-brown due to the f...

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  11. The pair(s) of reagents that yield paramagnetic species is/are

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  12. The product formed in the reaction of SOCl2 (thionyl chloride) with wh...

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  13. The compound (s) which generate (s) N(2) upon thermal decomposation is...

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  14. Which of the following compounds release reddish brown gas on heating?

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  15. Amongst H(2)O, H(2)S, H(2)Se and H(2)Te, the one with the highest boil...

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  16. The number of S -S bonds in sulphur trioxide trimer [S(3)O9] is

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  17. Which of the following oxoacid of sulphur had -O-O- linkage?

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  18. Which of the following is not oxidised by O(3)?

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  19. Which gas is evolved when PbO(2) is treated with conc HNO(3) ?

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  20. Aqueous solution of Na(2)S(2)O(3) on reaction with CI(2), gives

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