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With respect to protonic acids, which of...

With respect to protonic acids, which of the following statemets is correct ?

A

`PH_(3)` is more basic than `NH_(3)`

B

`PH_(3)` is less basic than `NH_(3)`

C

`PH_(3)` is equally basic as `NH_(3)`

D

`PH_(3)` is amphoteric while `NH_(3)` is basic

Text Solution

Verified by Experts

The correct Answer is:
B

`PH_(3)` is less basic than `NH_(3)` due to lessser availability of lone pair of electrons. The lone pair of electron is present in spherical s-orbital as compared to directional `sp^(3)` hybrid orbital in `NH_(3)`
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