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`underset("(1 e.q)")(CH_(3)-underset(O)underset(||)(C)-H)+underset("Excess")(H-underset(O)underset(||)(C)-H) overset(OH^(-))to ` product

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To solve the given question, we will follow these steps: ### Step 1: Identify the Reactants The reactants provided are: - Acetaldehyde (CH₃CHO) - Formaldehyde (HCHO) ### Step 2: Determine the Reaction Type The reaction taking place is an **aldol condensation**. This occurs when two aldehydes react in the presence of a base, leading to the formation of a β-hydroxy aldehyde (aldol) which can further dehydrate to form an α,β-unsaturated aldehyde. ### Step 3: Write the Reaction Mechanism 1. **Formation of Enolate Ion**: In a basic medium, acetaldehyde (CH₃CHO) will form an enolate ion. The base (OH⁻) abstracts a proton from the alpha carbon of acetaldehyde. \[ CH₃CHO + OH⁻ \rightarrow CH₂=CHO⁻ \] 2. **Nucleophilic Attack**: The enolate ion then acts as a nucleophile and attacks the carbonyl carbon of formaldehyde (HCHO). \[ CH₂=CHO⁻ + HCHO \rightarrow CH₂(OH)CH₂CHO \] 3. **Formation of Aldol**: The product formed is a β-hydroxy aldehyde (aldol). \[ CH₂(OH)CH₂CHO \quad \text{(3-hydroxybutanal)} \] ### Step 4: Dehydration to Form Alkene 4. **Dehydration**: The aldol product can undergo dehydration (loss of water) upon heating to form an α,β-unsaturated aldehyde. \[ CH₂(OH)CH₂CHO \xrightarrow{\Delta} CH₂=CHCHO + H₂O \] 5. **Final Product**: The final product after dehydration is crotonaldehyde (CH₂=CHCHO). ### Summary of the Reaction The overall reaction can be summarized as: - Starting from acetaldehyde and formaldehyde in basic medium, the aldol condensation occurs, leading to the formation of 3-hydroxybutanal, which upon heating gives crotonaldehyde. ### Final Products 1. **Aldol Product**: 3-hydroxybutanal (CH₂(OH)CH₂CHO) 2. **Dehydrated Product**: Crotonaldehyde (CH₂=CHCHO) ---
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RESONANCE ENGLISH-CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID -Part-1
  1. Write the product of the following reaction

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  2. (a) Cis-1,2-cylopentanediol reacts with acetone in the presence of dry...

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  3. Predict the product of following aldol condensation reaction : (a)CH...

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  4. Indicate the starting aldehyde or ketone from which each of the follow...

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  5. Predict the product from claisen condensation of the following pair of...

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  6. Predict the product for each of the following reactions

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  7. Identify the products in the following disproportional reaction and al...

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  8. underset("(1 e.q)")(CH(3)-underset(O)underset(||)(C)-H)+underset("Exce...

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  9. Write the product of the following reactions

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  10. PhCOCHBr(2)overset(OH^(-))toAoverset(OH^(-))toBoverset(H^(+))toC The...

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  12. Write the product of following reaction

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  13. Write the product of following reactions (a) CH3-CH(2)-OH overset(I(2...

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  14. In the following reactions prouct X and Y are

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  15. A compound D(C(8)H(10)O) upon treatement with alkaline solution of iod...

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  16. The product P of the following reaction is CH(3)-COOH overset(LiAlH(...

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  17. CH(3)COOH overset((i) PCl(3)+Cl(2) ("excess"))underset((ii) O(2))to (X...

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  18. The product (X) for the following conversion reactions is

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  19. Give the product of each of the following reactions Phthalic acid +N...

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  20. Predict the products of the following reactions.

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