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CH(3)CH(2)CH(2)CONH(2) is boiled with aq...

`CH_(3)CH_(2)CH_(2)CONH_(2)` is boiled with aqueous NaOH, then the reaction mixture is acidified with HCl. The products obtained are

A

`CH_(3)CH_(2)CH_(2)COO^(-)+NH_(3)`

B

`CH_(3)CH_(2)CH_(2)COONa+NH_(3)`

C

`CH_3CH_(2)CH_(2)COOH+NH_(4)Cl`

D

`CH_(3)CH_(2)CH_(2)COO^(-)+NH_(4)Cl`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reaction of the compound `CH₃CH₂CH₂CONH₂` (butanamide) when boiled with aqueous NaOH and then acidified with HCl. ### Step 1: Identify the Reactants The given compound is butanamide, which can be represented as: - **Butanamide**: `CH₃CH₂CH₂CONH₂` ### Step 2: Reaction with Aqueous NaOH When butanamide is boiled with aqueous NaOH, a hydrolysis reaction occurs. The hydroxide ions (OH⁻) from NaOH attack the carbonyl carbon of the amide group, leading to the formation of a carboxylate ion and ammonia. - The reaction can be represented as: \[ CH₃CH₂CH₂CONH₂ + NaOH \rightarrow CH₃CH₂CH₂COO^{-}Na^{+} + NH₄^{+} \] ### Step 3: Formation of Carboxylate Salt After the reaction with NaOH, we obtain a carboxylate salt (sodium butanoate) and ammonium ion: - **Carboxylate Salt**: `CH₃CH₂CH₂COO⁻Na⁺` - **Ammonium Ion**: `NH₄⁺` ### Step 4: Acidification with HCl Next, the mixture is acidified with HCl. The H⁺ ions from HCl will react with the carboxylate ion to form the corresponding carboxylic acid. - The reaction can be represented as: \[ CH₃CH₂CH₂COO^{-}Na^{+} + HCl \rightarrow CH₃CH₂CH₂COOH + NaCl \] ### Step 5: Products Obtained After the acidification, the products obtained are: 1. **Butanoic Acid**: `CH₃CH₂CH₂COOH` 2. **Ammonium Chloride**: `NH₄Cl` ### Final Answer The products obtained from the reaction are: - Butanoic Acid: `CH₃CH₂CH₂COOH` - Ammonium Chloride: `NH₄Cl` ### Summary of Products - **Main Product**: Butanoic Acid (`CH₃CH₂CH₂COOH`) - **By-product**: Ammonium Chloride (`NH₄Cl`)
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RESONANCE ENGLISH-CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID -Part-I
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  3. CH(3)CH(2)CH(2)CONH(2) is boiled with aqueous NaOH, then the reaction ...

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  4. In how many steps decarboxylation reaction is taking place

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  5. An alkene (A)C(16)H(16) on ozonolysis gives only one product (B)(C(8)H...

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  6. Compound (X) with molecular formula C(3)H(8)O is treated with acidifie...

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  8. A(C(6)H(12))overset(HCl)to underset((C(6)H(13)C))(B+C) B overset(alc...

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  9. In the following reaction

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  10. In conversion of 2-butanone to propanoic acid when reagent is used.

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  11. Identify (X) and (Y).

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  12. Which of the following reactants on reaction with conc. NaOH followed ...

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  13. Cyclohexene on ozonolysis followed by reaction with zinc dust and wate...

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  14. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  15. A teritary alcohol H upon acid catalysed dehydration gives a product I...

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  16. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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  17. A carbonyl compound P. which gives positive iodoform test, undergoes r...

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  18. A carbonyl compound P. which gives positive iodoform test, undergoes r...

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  19. A carbonyl compound P. which gives positive iodoform test, undergoes r...

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  20. Match each of the compounds given in ColumnI with reaction (s) that t...

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