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Number of possible intra molecular aldol...

Number of possible intra molecular aldol condensation product on heating with NaOH
`H_(3)C-overset(O)overset(||)(C)-CH_(2)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-H`

A

1

B

2

C

3

D

4

Text Solution

AI Generated Solution

The correct Answer is:
To determine the number of possible intramolecular aldol condensation products from the given compound, we can follow these steps: ### Step 1: Identify the Structure The compound given is: `H3C-C(=O)-C-CH2-CH2-CH2-C(=O)-H` This compound has two carbonyl groups (aldehydes) and a long carbon chain in between. ### Step 2: Recognize Aldol Condensation Aldol condensation involves the formation of an enolate ion from one carbonyl compound, which then attacks another carbonyl group to form a β-hydroxy carbonyl compound. This can happen intramolecularly if the structure allows for it. ### Step 3: Identify Possible Anions We need to find the different positions from which enolate ions can be formed. In this case, we can form anions from the following positions: 1. **From the first carbonyl (C=O) at the left end**: This will lead to an enolate that can attack the second carbonyl. 2. **From the second carbonyl (C=O) at the right end**: This will lead to an enolate that can attack the first carbonyl. 3. **From the carbon between the two carbonyls**: This carbon can also form an enolate and attack either of the carbonyls. ### Step 4: Count Unique Anions Now, we count the unique anions formed: - **Anion 1**: Formed from the first carbonyl (left). - **Anion 2**: Formed from the second carbonyl (right). - **Anion 3**: Formed from the carbon between the two carbonyls. ### Step 5: Determine the Number of Products Since the molecule is unsymmetrical, each of these anions can lead to a different aldol product. Therefore, we have a total of 3 unique anions leading to 3 unique products. ### Conclusion The number of possible intramolecular aldol condensation products is **3**. ### Final Answer **The answer is 3.** ---
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