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In the reaction sequences 2CH(3)CHO ov...

In the reaction sequences
`2CH_(3)CHO overset(OH^(-))toA overset(Delta)toB` the product B is

A

`CH_(3)-CH_(2)-CH_2-CH_(2)-OH`

B

`CH_(3)-CH=CH-CHO`

C

`CH_(3)-CH_(2)-CH_(2)-CH_3`

D

`CH_(3)-overset(O)overset(||)(C)-CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction sequence given in the question, which involves the condensation of acetaldehyde (CH₃CHO) in the presence of hydroxide ions (OH⁻) and subsequent heating. ### Step-by-Step Solution: 1. **Identify the Initial Reactant:** The initial reactant is acetaldehyde (CH₃CHO). We have 2 moles of it. 2. **Recognize the Reaction Type:** The reaction involves the aldol condensation. In the presence of a base (OH⁻), two molecules of acetaldehyde will undergo a condensation reaction. 3. **Formation of Beta-Hydroxy Aldehyde (Product A):** When 2 moles of acetaldehyde react, they form a beta-hydroxy aldehyde. The reaction can be represented as: \[ 2 \, \text{CH}_3\text{CHO} \xrightarrow{\text{OH}^-} \text{CH}_3\text{CH(OH)CH}_2\text{CHO} \] This product is known as 3-hydroxybutanal. 4. **Heating the Beta-Hydroxy Aldehyde:** Upon heating, the beta-hydroxy aldehyde undergoes dehydration (loss of water) to form an alpha, beta-unsaturated aldehyde (Product B). The dehydration reaction can be represented as: \[ \text{CH}_3\text{CH(OH)CH}_2\text{CHO} \xrightarrow{\Delta} \text{CH}_3\text{CH=CHCHO} + \text{H}_2\text{O} \] The product formed is 2-butenal (or crotonaldehyde), which has the structure CH₃CH=CHCHO. 5. **Identify the Final Product (B):** The final product B is therefore: \[ \text{CH}_3\text{CH=CHCHO} \] This corresponds to option B from the given choices. ### Conclusion: The product B is CH₃CH=CHCHO, which is an alpha, beta-unsaturated aldehyde.
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